20587-61-5Relevant articles and documents
Norton
, p. 4643 (1972)
Electrochemical esterification reaction of alkynes with diols: Via cleavage of carbon-carbon triple bonds without catalyst and oxidant
Cheng, Hui-Hui,Gao, Hui,Li, Pin-Hua,Shen, Hui-Zhi,Wang, Pei-Long
supporting information, p. 6783 - 6791 (2020/11/09)
A novel electrochemical esterification of alkynes for the synthesis of esters was developed in which diols and their derivatives were used as the partners. This method is green as it is catalyst-free, oxidant-free, and additive-free and shows atom-economy. This is the first example of an electrochemical reaction via cleavage of carbon-carbon triple bonds. Meanwhile, this is also the first example of a carbon-carbon triple bond cleavage reaction of alkynes with diols. This journal is
METHOD FOR PREPARING BENZOIC ACID ESTERS
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Page/Page column 14; 15; 16; 17; 18; 19; 20;, (2019/04/16)
The invention relates to the method of preparing benzoic acid esters which provides high selectivity of the process, and high yield of the desired product, as well as the reduction of the duration of the esterification process, comprising esterification of benzoic acid with monohydric alcohols having a number of carbon atoms from 6 to 12, or polyhydric alcohols having a number of carbon atoms from 2 to 10, in the presence of metal containing catalyst in the media of aromatic solvent at the stepwise buildup of the temperature of the process to 180-200°C, further to 200-220°C, and then to 240-250°C.