93547-88-7

Basic information

• Product Name: Silanol, (1,1-dimethylethyl)diphenyl-
• CAS NO: 93547-88-7
• Molecular Formula: C16H20OSi
• Molecular Weight: 256.42
• Mol File: 93547-88-7.mol
• Article Data: 29

Chemical Properties

• CAS DataBase Reference: Silanol, (1,1-dimethylethyl)diphenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Silanol, (1,1-dimethylethyl)diphenyl-(93547-88-7)
• EPA Substance Registry System: Silanol, (1,1-dimethylethyl)diphenyl-(93547-88-7)

Safety Data

• Hazardous Substances Data: 93547-88-7(Hazardous Substances Data)

Upstream product

• 75879-51-5 methyl 8R-tert-butyldiphenylsilyloxy-9S,11R-dihydroxy-9,11-O-isopropylidene-eicosa-5Z,12E,14Z-trienoate 
• 100-52-7 benzaldehyde 
• 1369432-39-2 (tert-butyldiphenylsilyl)(4-methoxyphenyl)methanol 
• 139706-45-9 benzyl tert-butyldiphenylsilyl ether 
• 33729-92-9 tert-butyldiphenylsilane 
• 389890-43-1 tert-butyl (1,3-cis)-N-(3-hydroxycyclobutyl)carbamate 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 1609644-50-9 C₃₉H₄₆N₂O₅Si 
• 112440-16-1 1-<(1',1'-dimethylethyl)diphenylsilyl>acetylene 
• 167865-74-9 tert-butyl(diphenyl)silylethene 
• 1413917-19-7 N-[(1,1-dimethylethyl)diphenylsilyl]-4-nitrobenzaldimine 
• 119645-09-9 N-[(1,1-dimethylethyl)diphenylsilyl]benzenemethanamine 
• 110-91-8 morpholine 
• 1413917-21-1 N-[(1,1-dimethylethyl)diphenylsilyl]-3(4-nitrophenyl)oxaziridine 

Downstream Products

• 111742-19-9 tert-butyl(4-nitrophenyl)phenylsilanol 
• 111742-18-8 tert-butyl(3-nitrophenyl)phenylsilanol 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 1246993-02-1 2-(tert-butyldiphenylsilyloxy)-4-phenyl-N-(2,4,4-trimethylpentan-2-yl)butanamide 
• 1310096-08-2 NMo(OSi(C₆H₅)2C(CH₃)3)3 
• 315191-15-2 1-tert-butyl-3,3-dimethyl-1,1-diphenyldisiloxane 

Relevant articles and documents

A 3D Organically Synthesized Porous Carbon Material for Lithium-Ion Batteries

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Silicon-center chiral silicon-oxygen compound and preparation method thereof

The invention belongs to the field of chiral silicon synthesis, and discloses a silicon-center chiral silicon-oxygen compound. The compound has a structure represented by general formula I shown in the specification. In the formula I, X is Si(R)n or a formula also shown in the specification, R is selected from alkyl, cycloalkyl and aryl, R is selected from alkyl, substituted phenyl and aryl, R is selected from alkyl, phenyl and substituted phenyl, n is 3, the three R are the same or different, R is selected from hydrogen and (C1-C4) alkyl, m is selected from 0, 1, 2 and 3, and Y is selected from substituted phenyl, substituted pyrenyl, aryl, heteroaryl and cycloalkyl. The invention also discloses a preparation method of the compound. Various highly functionalized chiral siloxanes and silyl ethers are obtained with good chemical, regional and stereo control and high yield, the variety of silicon center chiral compounds is expanded, and the method has the advantages of high enantioselectivity, wide substrate application range, mild reaction conditions, atom economy and the like. In addition, the compound provided by the invention has a huge application prospect in chiral organic photoelectric materials.

Highly Selective Hydroxylation and Alkoxylation of Silanes: One-Pot Silane Oxidation and Reduction of Aldehydes/Ketones

An efficient chemoselective iridium-catalyzed method for the hydroxylation and alkoxylation of organosilanes to generate hydrogen gas and silanols or silyl ethers was developed. A variety of sterically hindered silanes with alkyl, aryl, and ether groups were tolerated. Furthermore, this atom-economical catalytic protocol can be used for the synthesis of silanediols and silanetriols. A one-pot silane oxidation and chemoselective reduction of aldehydes/ketones was also realized.