995-25-5

Basic information

• Product Name: TRI-N-PROPYLCHLOROSILANE
• Synonyms: CHLOROTRIPROPYLSILANE;CHLOROTRI-N-PROPYLSILANE;TRIPROPYLCHLOROSILANE;TRI-N-PROPYLCHLOROSILANE;chlorotripropyl-silan;Chlorotri-n-propylsilane,98%;tri-n-propylsilyl chloride;Tripropylsilyl chloride
• CAS NO: 995-25-5
• Molecular Formula: C₉H₂₁ClSi
• Molecular Weight: 192.8
• EINECS: 213-624-5
• Mol File: 995-25-5.mol

Chemical Properties

• Boiling Point: 202 °C(lit.)
• Flash Point: 76°C
• Appearance: Colorless liquid
• Density: 0.882 g/mL at 25 °C(lit.)
• Vapor Pressure: 0.329mmHg at 25°C
• Refractive Index: n20/D 1.44(lit.)
• Sensitive: Moisture Sensitive
• BRN: 1737489
• CAS DataBase Reference: TRI-N-PROPYLCHLOROSILANE(CAS DataBase Reference)
• NIST Chemistry Reference: TRI-N-PROPYLCHLOROSILANE(995-25-5)
• EPA Substance Registry System: TRI-N-PROPYLCHLOROSILANE(995-25-5)

Safety Data

• Hazard Codes: C
• Statements: 14-35-37
• Safety Statements: 26-36/37/39-45
• RIDADR: UN 2987 8/PG 2
• WGK Germany: 1
• F: 10-21
• TSCA: Yes
• HazardClass: 8
• PackingGroup: II
• Hazardous Substances Data: 995-25-5(Hazardous Substances Data)

Usage

Uses

Used in Silicon-based Material Production:
TRI-N-PROPYLCHLOROSILANE is used as a precursor for the production of various silicon-based materials and compounds. Its role in this application is crucial due to its ability to initiate the formation of these materials, which are essential in numerous industries.
Used in the Semiconductor Industry:
In the semiconductor industry, TRI-N-PROPYLCHLOROSILANE is utilized as a reagent for surface modification. It helps in altering the properties of semiconductor surfaces to improve their performance in electronic devices.
Used as a Coupling Agent:
TRI-N-PROPYLCHLOROSILANE also functions as a coupling agent for the binding of organic and inorganic materials. This dual capability allows for the creation of hybrid materials with unique properties that can be tailored for specific applications.
Used in Specialty Chemicals and Functionalized Polymers Synthesis:
Furthermore, TRI-N-PROPYLCHLOROSILANE is employed in the synthesis of specialty chemicals and functionalized polymers. Its involvement in these processes contributes to the development of advanced materials with specialized properties for various high-tech applications.

InChI:InChI=1/C9H21ClSi/c1-4-7-11(10,8-5-2)9-6-3/h4-9H2,1-3H3

Upstream product

• 17841-51-9 hexapropyl-disiloxane 
• 17906-15-9 cyclohexyloxy-tripropyl-silane 
• 122-04-3 4-nitro-benzoyl chloride 
• 18023-47-7 ethoxy-tripropyl-silane 
• 75-36-5 acetyl chloride 
• 998-29-8 tripropylsilane 
• 994-66-1 tetrapropylsilane 
• 994-30-9 triethylsilyl chloride 
• 2327-99-3 1-phenylpropadiene 
• 429-88-9 tripropylfluorosilane 

Downstream Products

• 109928-24-7 1,1-bis(4-tert-butylphenyl)-4-(tri-n-propylsilyl)-1-silacyclo-2-pentene 
• 109928-09-8 1,1-bis(4-tert-butylphenyl)-2-(tri-n-propylsilyl)-1-silacyclo-3-pentene 
• 100-42-5 styrene 
• 497180-91-3 tripropyl-m-tolyl-silane 
• 17897-71-1 tripropyl-p-tolyl-silane 
• 497180-92-4 tripropyl-o-tolyl-silane 
• 18105-48-1 allyltripropylsilane 
• 17902-83-9 phenoxy-tripropyl-silane 
• 873-66-5 1-propenylbenzene 
• 16002-93-0 (E)-1-phenyl-1-pentene 
• 300-57-2 allylbenzene 

Relevant articles and documents

Neutral-Eosin-Y-Photocatalyzed Silane Chlorination Using Dichloromethane

Chlorosilanes are versatile reagents in organic synthesis and material science. A mild pathway is now reported for the quantitative conversion of hydrosilanes to silyl chlorides under visible-light irradiation using neutral eosin Y as a hydrogen-atom-transfer photocatalyst and dichloromethane as a chlorinating agent. Stepwise chlorination of di- and trihydrosilanes was achieved in a highly selective fashion assisted by continuous-flow micro-tubing reactors. The ability to access silyl radicals using photocatalytic Si?H activation promoted by eosin Y offers new perspectives for the synthesis of valuable silicon reagents in a convenient and green manner.

Silylation and alkylation of allenes using chlorosilanes and alkyl halides in the presence of palladium catalyst and Grignard reagents

Allenes react with Grignard reagents and chlorosilanes in the presence of a palladium catalyst giving rise to carbosilylated products bearing carbon groups from Grignard reagents at the central carbon and silyl groups at the terminal carbon. When alkyl halides were used instead of chlorosilanes, the corresponding alkylated products were obtained.

SELECTIVE REDISTRIBUTION REACTIONS OF ORGANOSILANES IN THE PRESENCE OF CHLOROPLATINIC ACID

Tetrasubstituted silanes of the general formula R2SiR'2 undergo redistribution reactions quite selectively in the presence of SiHCl3 and chloroplatinic acid.It is the smallest and seemingly the least hindered of the R groups on the tetrasubstituted silane which exchange most readily with a chloro group on trichlorosilane.