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Cadmium hydroxide

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Name

Cadmium hydroxide

EINECS 244-168-5
CAS No. 21041-95-2 Density 4.79 g/cm3
PSA 40.46000 LogP -0.35610
Solubility water: 0.026 g/100 mL Melting Point 130 °C
Formula CdH2O2 Boiling Point 300 °C
Molecular Weight 146.42 Flash Point N/A
Transport Information UN 2570 Appearance white crystal or powder
Safety 60-61 Risk Codes 20/21/22-50/53
Molecular Structure Molecular Structure of 21041-95-2 (Cadmium hydroxide) Hazard Symbols HarmfulXn,DangerousN
Synonyms

Cadmiumhydroxide (8CI);Cadmium dihydroxide;AI3-09097;401560_ALDRICH;CID62749;LS-48529;

 

Cadmium hydroxide Consensus Reports

IARC Cancer Review: Group 1 IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 58 , 1993,p. 119.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Animal Sufficient Evidence IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 58 , 1993,p. 119.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Human Sufficient Evidence IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 58 , 1993,p. 119.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) . Reported in EPA TSCA Inventory.

Cadmium hydroxide Specification

The Cadmium hydroxide with CAS registry number of 21041-95-2 is also known as Cadmium (II) hydroxide. The IUPAC name is Cadmium dihydrate. It belongs to product categories of Cadmium Salts; CadmiumMetal and Ceramic Science; Catalysis and Inorganic Chemistry; Chemical Synthesis; Salts. Its EINECS registry number is 244-168-5. In addition, the formula is CdH2O2 and the molecular weight is 146.42. This chemical is a white crystal or powder and should be stored in sealed containers in cool, dry place and away from oxidizing agents, acid and water.

Physical properties about Cadmium hydroxide are: (1)ACD/LogP: -1.38; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): -1.38; (4)ACD/LogD (pH 7.4): -1.38; (5)ACD/BCF (pH 5.5): 1; (6)ACD/BCF (pH 7.4): 1; (7)#H bond acceptors: 1; (8)#H bond donors: 2; (9)#Freely Rotating Bonds: 0; (10)Polar Surface Area: 20.23Å2; (11)Enthalpy of Vaporization: 40.65 kJ/mol; (12)Boiling Point: 100 °C at 760 mmHg; (13)Vapour Pressure: 24.5 mmHg at 25 °C.

Preparation of Cadmium hydroxide: it is prepared by treating cadmium nitrate with sodium hydroxide. Cadmium hydroxide is more basic than zinc hydroxide for attempting preparation from other cadmium salts. When treated with concentrated caustic soda solution, it forms the anionic complex Cd(OH)42-.

 Cd(NO3)2 + 2NaOH → Cd(OH)2 + 2NaNO3

Uses of Cadmium hydroxide: it is generated in storage battery anodes, in nickel-cadmium and silver-cadmium storage batteries in its discharge. The hydroxide is used in place of cadmium oxide for variety of operations.

Ni(OH)2 + Cd → Cd(OH)2 + Ni

When you are using this chemical, please be cautious about it. As a chemical, it is harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. What's more, it is harmful by inhalation, in contact with skin and if swallowed. During using it, this material and its container must be disposed of as hazardous waste and avoid release to the environment.

You can still convert the following datas into molecular structure:
1. SMILES: [Cd+2].[OH-].[OH-]
2. InChI: InChI=1/Cd.2H2O/h;2*1H2/q+2;;/p-2
3. InChIKey: PLLZRTNVEXYBNA-NUQVWONBAA
4. Std. InChI: InChI=1S/Cd.2H2O/h;2*1H2/q+2;;/p-2
5. Std. InChIKey: PLLZRTNVEXYBNA-UHFFFAOYSA-L

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