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Chloroplatinic acid

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Name

Chloroplatinic acid

EINECS 241-010-7
CAS No. 16941-12-1 Density 2.43 g/mL at 25 °C(lit.)
PSA 0.00000 LogP -3.23650
Solubility 0.5 M at 20 °C, clear, orange in water Melting Point 60 °C(lit.)
Formula H2PtCl6 Boiling Point N/A
Molecular Weight 409.814 Flash Point N/A
Transport Information UN 3264 8/PG 3 Appearance Orange/Red Crystals
Safety 26-27-36/37/39-45-22 Risk Codes 25-34-42/43
Molecular Structure Molecular Structure of 16941-12-1 (Chloroplatinic acid) Hazard Symbols ToxicT,CorrosiveC,IrritantXi
Synonyms

Chloroplatinic(IV)acid (6CI);Platinate(2-),hexachloro-, dihydrogen, (OC-6-11)- (9CI);Dihydrogen hexachloroplatinate;Hexachloroplatinic acid;Hexachloroplatinic(IV) acid;Hydrogen hexachloroplatinate;Hydrogenplatinum chloride (H2PtCl6);Platinic acid (H2PtCl6);Platinum chloride (H2PtCl6);

 

Chloroplatinic acid Consensus Reports

Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program.

Chloroplatinic acid Standards and Recommendations

OSHA PEL: TWA 0.002 mg(Pt)/m3
ACGIH TLV: TWA 0.002 mg(Pt)/m3
DOT Classification:  8; Label: Corrosive

Chloroplatinic acid Specification

The Chloroplatinic acid, with the CAS registry number 16941-12-1 and EINECS registry number 241-010-7, has the systematic name of dihydrogen hexachloroplatinate(2-). The molecular formula of this chemical is H2PtCl6. It is a kind of orange or red crystals, and may decompose on exposure to light, air or moisture. What's more, it  is the chemical compound usually found as the hexahydrate with the formula H2PtCl6.(H2O)6. And it is one of the most readily available soluble compounds of platinum.

The physical properties of Chloroplatinic acid are as following: (1)ACD/LogP: -1.03; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): -5.53; (4)ACD/LogD (pH 7.4): -5.53; (5)ACD/BCF (pH 5.5): 1; (6)ACD/BCF (pH 7.4): 1 ; (7)#H bond acceptors: 4; (8)#H bond donors: 2; (9)#Freely Rotating Bonds: 0; (10)Polar Surface Area: 82.98 Å2; (11)Enthalpy of Vaporization: 62.94 kJ/mol; (12)Boiling Point: 330 °C at 760 mmHg; (13)Vapour Pressure: 3.35E-05 mmHg at 25°C.

Preparation of Chloroplatinic acid: It can be produced by dissolving platinum metal sponge in aqua regia. This reaction is rumored to produce nitrogen-containing platinum compounds, but the product is H2PtCl6.
Pt + 4HNO3 + 6 HCl → H2PtCl6 + 4NO2 + 4H2O

Uses of Chloroplatinic acid: It is often used in the potassium determination, purification of platinum, and it is also used as a catalyst precursor in some organic synthesis.

You should be cautious while dealing with this chemical. It is toxic if swallowed, and may cause burns. It may also cause sensitization by inhalation and skin contact. Therefore, you had better take the following instructions: Do not breathe dust; Wear suitable protective clothing, gloves and eye/face protection, and in case of contacting with eyes, rinse immediately with plenty of water and seek medical advice; In case of accident or if you feel unwell, seek medical advice immediately (show label where possible).

You can still convert the following datas into molecular structure:
(1)SMILES: [H+].[H+].Cl[Pt-2](Cl)(Cl)(Cl)(Cl)Cl
(2)InChI: InChI=1/6ClH.Pt/h6*1H;/q;;;;;;+4/p-4/rCl6Pt/c1-7(2,3,4,5)6/q-2/p+2
(3)InChIKey: GBFHNZZOZWQQPA-DUMOQKOKAQ

The toxicity data is as follows:

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LD50 intraperitoneal 29097mg/kg (29097mg/kg)   Comptes Rendus Hebdomadaires des Seances, Academie des Sciences. Vol. 256, Pg. 1043, 1963.
rabbit LDLo intravenous 125mg/kg (125mg/kg)   Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975.
rat LD50 intravenous 49mg/kg (49mg/kg) SENSE ORGANS AND SPECIAL SENSES: OTHER CHANGES: OLFACTION

BEHAVIORAL: TREMOR

GASTROINTESTINAL: "HYPERMOTILITY, DIARRHEA"
National Technical Information Service. Vol. PB291-731.

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