Welcome to LookChem.com Sign In|Join Free
  • or
Home > Products >  > 

Cupric acetate

Related Products

Hot Products

Name

Cupric acetate

EINECS 205-553-3
CAS No. 142-71-2 Density 1.068g/cm3
PSA 37.30000 LogP 0.08840
Solubility Soluble in water and alcohol. Slightly soluble in ether and glycerol. Melting Point 115 °C
Formula C4H6CuO4 Boiling Point 117.1 °C at 760 mmHg
Molecular Weight 363.27 Flash Point 40 °C
Transport Information UN 3077 9/PG 3 Appearance Green crystalline powder
Safety 26-60-61 Risk Codes 22-36/37/38-50/53
Molecular Structure Molecular Structure of 142-71-2 (Cupric acetate) Hazard Symbols HarmfulXn, DangerousN
Synonyms

Aceticacid, copper(2+) salt (8CI,9CI);Copper acetate (Cu(OAc)2) (7CI);Acetic acidcupric salt;Copper acetate (Cu(C2H3O2)2);Copper acetate(Cu(MeCO2)2);Copper diacetate;Copper(2+) acetate;Copper(2+) diacetate;Copper(II) acetate;Crystallized verdigris;Crystals of Venus;Cupric diacetate;Neutral verdigris;Venus copper;

Article Data 95

Cupric acetate Synthetic route

copper(II) nitrate trihydrate

108-24-7

acetic anhydride

142-71-2

copper diacetate

Conditions
ConditionsYield
In acetic anhydride reflux; washed with acetic anhydride and ether;;93%
In acetic anhydride reflux; washed with acetic anhydride and ether;;93%
In neat (no solvent) on warming;;
In neat (no solvent) on warming;;

[Cu(NO2)(OCHC6H4P(C6H5)2)2]

64-19-7

acetic acid

A

142-71-2

copper diacetate

B

10102-44-0

Nitrogen dioxide

Conditions
ConditionsYield
In dichloromethane N2, acid added at room temp.;A n/a
B 85%
108-24-7

acetic anhydride

A

diacetyl-orthonitric acid

B

142-71-2

copper diacetate

Conditions
ConditionsYield
With copper(II) nitrate at 30 - 35℃;
108-24-7

acetic anhydride

142-71-2

copper diacetate

Conditions
ConditionsYield
With copper(II) nitrate
108-24-7

acetic anhydride

Cu(NO3)2+3H2O

Cu(NO3)2+3H2O

A

diacetyl-orthonitric acid

B

142-71-2

copper diacetate

Conditions
ConditionsYield
at 30 - 45℃;
75-15-0

carbon disulfide

938-81-8

N-nitrosoacetanilide

copper

copper

142-71-2

copper diacetate

56-23-5

tetrachloromethane

938-81-8

N-nitrosoacetanilide

copper

copper

A

142-71-2

copper diacetate

B

copper (II)-ion

copper (II)-ion

C

copper chloride

copper chloride

Cu(C2H3O2)2+2 NH3

Cu(C2H3O2)2+2 NH3

142-71-2

copper diacetate

Cu(C2H3O2)2+H2O

Cu(C2H3O2)2+H2O

142-71-2

copper diacetate

Conditions
ConditionsYield
With toluene azeotrope Destillation;

copper(II) acetate tetrahydrate

142-71-2

copper diacetate

Conditions
ConditionsYield
In neat (no solvent, solid phase) byproducts: H2O; acetate was heated in vac. at 150°C for 3 h;

Cupric acetate History

 Copper(II) acetate (CAS NO.142-71-2) is occasionally the primary component of verdigris, the blue-green substance that forms on copper during long exposures to atmosphere. It was historically prepared in vineyards, since acetic acid is a byproduct of fermentation.Copper (cupric) acetate tablets were believed to repel sharks in the mid twentieth century.

Cupric acetate Consensus Reports

Reported in EPA TSCA Inventory. Copper and its compounds are on the Community Right-To-Know List.

Cupric acetate Standards and Recommendations

ACGIH TLV: TWA 1 mg(Cu)/m3

Cupric acetate Specification

The IUPAC name of this chemical is copper diacetate. With the CAS registry number 142-71-2, it is also named as Acetate de cuivre. The product's categorie is organic-metal salt. It is green crystalline powder which is soluble in water and ethanol, slightly soluble in ether and glycerol. In addition, it is highly toxic and the storage environment should be ventilate, low-temperature and dry. Keep Copper(II) acetate separate from acids.

The other characteristics of this product can be summarized as: (1)ACD/LogP: -0.29; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): -1.07; (4)ACD/LogD (pH 7.4): -2.86; (5)ACD/BCF (pH 5.5): 1; (6)ACD/BCF (pH 7.4): 1; (7)ACD/KOC (pH 5.5): 2.73; (8)ACD/KOC (pH 7.4): 1; (9)#H bond acceptors: 2; (10)#H bond donors: 1; (11)#Freely Rotating Bonds: 0; (12)Flash Point: 40 °C; (13)Enthalpy of Vaporization: 23.7 kJ/mol; (14)Boiling Point: 117.1 °C at 760 mmHg; (15)Vapour Pressure: 13.9 mmHg at 25°C; (16)Exact Mass: 180.95621; (17)MonoIsotopic Mass: 180.95621; (18)Topological Polar Surface Area: 80.3; (19)Heavy Atom Count: 9; (20)Complexity: 25.5.

Preparation of Copper(II) acetate: It has been synthesized for centuries by the method described in the history section. The overall reaction is as follows:
2 CuSO4.5H2O + 4 NH3 + 4 C2H4O → Cu2(OAc)4(H2O)2 + 2 (NH4)2SO4 + 8 H2O
The hydrate form can be dehydrated by heating at 100 °C in a vacuum:
Cu2(OAc)4(H2O)2 → Cu2(OAc)4 + 2 H2O
Heating a mixture of anhydrous Cu2(OAc)4 and copper metal affords colorless, volatile cuprous acetate:
2 Cu + Cu2(OAc)4 → 4 CuOAc

Uses of Copper(II) acetate: It is used as an insecticide, in the preparation of other chemicals, as a fungicide, and mildew preventive, fungicides, printing and dyeing fixing agent. And it also has been used as intermediate to prepare Paris green.

When you are using this chemical, please be cautious about it as the following: 
It is not only harmful if swallowed, but also irritating to eyes, respiratory system and skin. And it is also very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. This material and its container must be disposed of as hazardous waste. Additionally, people should avoid release to the environment. 

People can use the following data to convert to the molecule structure. 
1. SMILES:[Cu+2].[O-]C(=O)C.[O-]C(=O)C
2. InChI:InChI=1/2C2H4O2.Cu/c2*1-2(3)4;/h2*1H3,(H,3,4);/q;;+2/p-2
3. InChIKey:OPQARKPSCNTWTJ-NUQVWONBAO

The following are the toxicity data which has been tested.

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LD50 intraperitoneal 2500ug/kg (2.5mg/kg)   Biochemical Pharmacology. Vol. 30, Pg. 771, 1981.
mouse LD50 intravenous 20mg/kg (20mg/kg) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD
Indian Journal of Pharmacology. Vol. 23, Pg. 153, 1991.
mouse LD50 oral 196mg/kg (196mg/kg) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD
Indian Journal of Pharmacology. Vol. 23, Pg. 153, 1991.
rabbit LDLo oral 250mg/kg (250mg/kg)   Journal of Medical Research. Vol. 42, Pg. 461, 1919.
rat LD50 intraperitoneal 14700ug/kg (14.7mg/kg) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD
Indian Journal of Pharmacology. Vol. 23, Pg. 153, 1991.
rat LD50 intravenous 17100ug/kg (17.1mg/kg) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD
Indian Journal of Pharmacology. Vol. 23, Pg. 153, 1991.
rat LD50 oral 501mg/kg (501mg/kg) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD
Indian Journal of Pharmacology. Vol. 23, Pg. 153, 1991.
rat LD50 subcutaneous 350mg/kg (350mg/kg) MUSCULOSKELETAL: JOINTS Progress in Medical Chemistry. Vol. 15, Pg. 211, 1977.

Post a RFQ

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

1

What can I do for you?
Get Best Price

Get Best Price for 142-71-2