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Cyclohexane, 1,2-dibromo-, (1R,2R)-rel-

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Name

Cyclohexane, 1,2-dibromo-, (1R,2R)-rel-

EINECS 231-070-2
CAS No. 7429-37-0 Density 1.789 g/cm3
PSA 0.00000 LogP 3.08740
Solubility N/A Melting Point -5 °C
Formula C6H10Br2 Boiling Point 220.5 °C at 760 mmHg
Molecular Weight 296.045 Flash Point 91.5 °C
Transport Information N/A Appearance Colourless to light yellow liquid
Safety 24/25 Risk Codes N/A
Molecular Structure Molecular Structure of 7429-37-0 (TRANS-1,2-DIBROMOCYCLOHEXANE) Hazard Symbols N/A
Synonyms

Cyclohexane, 1,2-dibromo-, trans- (8CI);(1R,2R)-1,2-Dibromocyclohexane;Cyclohexane, 1,2-dibromo-, (1R,2R)-;NSC 92176;trans-1,2-Dibromocyclohexane;Cyclohexane,1,2-dibromo-,trans-;AC1Q23RX;AC1L407Y;CID98506;

Article Data 113

Cyclohexane, 1,2-dibromo-, (1R,2R)-rel- Specification

The Cyclohexane, 1,2-dibromo-, (1R,2R)-rel- with CAS registry number of 7429-37-0 is also known as trans-1,2-Dibromocyclohexane. The IUPAC name is (1R,2R)-1,2-Dibromocyclohexane. It belongs to product categories of Alkyl; Halogenated Hydrocarbons; Organic Building Blocks. Its EINECS registry number is 231-070-2. In addition, the formula is C6H10Br2 and the molecular weight is 241.95. This chemical is a colourless to light yellow liquid and should be sealed in cool, dry place. What's more, it is used as intermediate in organic synthesis. During using it, avoid contact with skin and eyes.

Physical properties about Cyclohexane, 1,2-dibromo-, (1R,2R)-rel- are: (1)ACD/LogP: 3.26; (2)ACD/LogD (pH 5.5): 3.26; (3)ACD/LogD (pH 7.4): 3.26; (4)ACD/BCF (pH 5.5): 175.63; (5)ACD/BCF (pH 7.4): 175.63; (6)ACD/KOC (pH 5.5): 1406.98; (7)ACD/KOC (pH 7.4): 1406.98; (8)Index of Refraction: 1.552; (9)Molar Refractivity: 43.24 cm3; (10)Molar Volume: 135.1 cm3; (11)Surface Tension: 41.1 dyne/cm; (12)Density: 1.789 g/cm3; (13)Flash Point: 91.5 °C; (14)Enthalpy of Vaporization: 43.84 kJ/mol; (15)Boiling Point: 220.5 °C at 760 mmHg; (16)Vapour Pressure: 0.166 mmHg at 25 °C.

Preparation of Cyclohexane, 1,2-dibromo-, (1R,2R)-rel-: Firstly, adding cyclohexene, carbon tetrachloride and ethanol to beaker. Then bromine and carbon tetrachloride solution is added dropwise in 3 hours at the temperature below 1 °C. After reaction, carbon tetrachloride is steamed in water bath and the residue is washed by 20% potassium hydroxide solution and water. At last, product is obtained by vacuum distillation and drying. The yield is about 85%.

You can still convert the following datas into molecular structure:
1. SMILES: Br[C@@H]1CCCC[C@H]1Br
2. InChI: InChI=1/C6H10Br2/c7-5-3-1-2-4-6(5)8/h5-6H,1-4H2/t5-,6-/m1/s1
3. InChIKey: CZNHKZKWKJNOTE-PHDIDXHHBK

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