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(R)-2-azido-2-phenylacetic acid
(R)-phenylglycine
Conditions | Yield |
---|---|
With hydrogen; palladium on activated charcoal In water; acetic acid under 760 Torr; for 3h; | 97% |
Conditions | Yield |
---|---|
With nitrilase AY487533 In aq. acetate buffer at 20℃; for 1h; pH=8; Enzymatic reaction; enantioselective reaction; | 96.5% |
(R)-phenylglycine
Conditions | Yield |
---|---|
With hydrogenchloride; water In water at 110℃; for 3h; optical yield given as %ee; | 94% |
Boc-D-Phg-OH
(R)-phenylglycine
Conditions | Yield |
---|---|
With trifluoroacetic acid for 0.333333h; | 89% |
With hydrogenchloride; Dowex 50*8 1.) THF, room temperature, 2 h.; Yield given. Multistep reaction; |
6-Aminopenicillanic Acid
(R)-phenylglycine amide
A
(R)-phenylglycine
B
ampicillin
Conditions | Yield |
---|---|
With A. faecalis; immobilised penicillin acylase (EC 3.5.1.11) In water; acetonitrile at 0℃; Product distribution; Kinetics; Further Variations:; Solvents; reusing run; Enzymatic reaction; | A n/a B 86% |
N-(2,4,6-trimethyl-benzenesulfonyl)-D-phenylglycine
(R)-phenylglycine
Conditions | Yield |
---|---|
With sodium naphthalenide In 1,2-dimethoxyethane at -40℃; for 0.5h; | 78% |
(R)-(furan-2-yl)(phenyl)methanamine
(R)-phenylglycine
Conditions | Yield |
---|---|
With ozone In methanol at -78℃; for 0.25h; | 78% |
N-acetyl-α-phenylglycine
(R)-phenylglycine
Conditions | Yield |
---|---|
With water at 30℃; for 26h; D-aminoacylase from Streptomyces tuirus IFO 13418; | 74% |
MANDELIC ACID
(R)-phenylglycine
Conditions | Yield |
---|---|
With D-glucose; ammonia; ammonium chloride In aq. phosphate buffer at 30℃; for 24h; pH=8; Catalytic behavior; Reagent/catalyst; Microbiological reaction; Green chemistry; Enzymatic reaction; enantioselective reaction; | 71% |
[(1R)-2-(benzyloxy)-2-oxo-1-phenylethyl]ammonium 4-methyl-1-benzensulfonate
(R)-phenylglycine
Conditions | Yield |
---|---|
With hydrogenchloride Heating; | 69% |
IUPAC Name: (2R)-2-azaniumyl-2-phenylacetate
Empirical Formula: C8H9NO2
Molecular Weight: 151.1626g/mol
EINECS: 212-876-3
Structure of D-2-Phenylglycine (CAS NO.875-74-1):
Index of Refraction: 1.589
Molar Refractivity: 40.9 cm3
Molar Volume: 121.3 cm3
Polarizability: 16.21×10-24cm3
Surface Tension: 57 dyne/cm
Density: 1.246 g/cm3
Flash Point: 128.4 °C
Enthalpy of Vaporization: 55.75 kJ/mol
Melting Point: 302 °C (dec.)(lit.)
Boiling Point: 288.7 °C at 760 mmHg
Vapour Pressure: 0.00107 mmHg at 25°C
Water Solubility: 0.3g/100mL
Product Categories: GLYCINESCAFFOLD;Pharmaceutical Intermediates;Amino ACIDS SERIES;Phenylglycine [Phg];Unusual Amino Acids;Amino Acids
Canonical SMILES: C1=CC=C(C=C1)C(C(=O)[O-])[NH3+]
Isomeric SMILES: C1=CC=C(C=C1)[C@H](C(=O)[O-])[NH3+]
InChI: InChI=1S/C8H9NO2/c9-7(8(10)11)6-4-2-1-3-5-6/h1-5,7H,9H2,(H,10,11)/t7-/m1/s1
InChIKey: ZGUNAGUHMKGQNY-SSDOTTSWSA-N
Hazard Codes: T
Risk Statements: 23/24/25-36/37/38
R23/24/25:Toxic by inhalation, in contact with skin and if swallowed.
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements: 22-24/25-45-36/37/39-26
S22:Do not breathe dust.
S24/25:Avoid contact with skin and eyes.
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
WGK Germany: 3
HS Code: 29224995
D-2-Phenylglycine , its cas register number is 875-74-1. It also can be called Benzeneacetic acid, alpha-amino-, (alphaR)- ;
D-(-)-alpha-Phenylglycine . D-2-Phenylglycine (CAS NO.875-74-1) is a white crystalline powder.