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Dicyclohexylammonium nitrite

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  • Name Dicyclohexylammonium nitrite
  • EINECS221-515-9
  • CAS No. 3129-91-7
  • Density0.91g/cm3
  • PSA61.69000
  • LogP3.77430
  • Solubility39 g/l (soluble in alcohols) 2 and NOx. See also NITRITES.
  • Risk Codes20/22
  • Molecular Structure
    Molecular Structure of 3129-91-7 (Dicyclohexylammonium nitrite)
  • Hazard Symbols4.1 (Packing Group: III) UN NO.
  • Synonyms4.1 (Packing Group: III) UN NO.

Dicyclohexylammonium nitrite Synthetic route

3129-91-7

dicyclohexylamine nitrite

A

64-19-7

acetic acid

B

802294-64-0

propionic acid

C

79-31-2

isobutyric Acid

D

107-92-6

butyric acid

E

109-52-4

valeric acid

Conditions
ConditionsYield
With ozone In water at 40℃; for 1.16667h; Product distribution; diff. concentrations of O3; diff. reaction time; influence of alkaline;

Dicyclohexylammonium nitrite Chemical Properties

Product Name: Dicyclohexylammonium nitrite (CAS NO.3129-91-7)


Molecular Formula: C12H24N2O2
Molecular Weight: 228.33g/mol
Mol File: 3129-91-7.mol
Einecs: 221-515-9
Appearance: White to light-colored crystalline solid
Melting Point: 188-194 °C (dec.)
Boiling point: 256.1 °C at 760 mmHg
Flash Point: 96.1 °C
Enthalpy of Vaporization: 49.36 kJ/mol
Vapour Pressure: 0.0157 mmHg at 25°C
H-Bond Donor: 2
H-Bond Acceptor: 4
Product Categories: Pharmaceutical Intermediates; Intermediates of Dyes and Pigments; Aromatic Esters

Dicyclohexylammonium nitrite Uses

 Dicyclohexylammonium nitrite (CAS NO.3129-91-7) can be used as vapor phase corrosion inhibitor. It is mainly used for metal corrosion protection and to prevent metal corrosion to continue. Eg for motor vehicles and parts, deceleration chassis, internal combustion engines, machine tools, cutting tools measuring tools, etc. can also be used in weapons, radar and other equipment of the metal protection. Vapor corrosion inhibitor with excellent performance, long period of anti-rust, anti-rust effect is good, complex and simple components are suitable. But it was brass, tin and its alloys are corrosion.

Dicyclohexylammonium nitrite Production

 Dicyclohexylammonium nitrite (CAS NO.3129-91-7) consists of dicyclohexylamine reaction with phosphoric acid dicyclohexylamine, and then adding sodium nitrite dicyclohexylamine nitrite reaction: reaction products after washing and drying was finished.

Dicyclohexylammonium nitrite Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
cat LDLo oral 50mg/kg (50mg/kg)   "Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982Vol. -, Pg. 50, 1982.
guinea pig LD50 oral 350mg/kg (350mg/kg) BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD

LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES

BEHAVIORAL: MUSCLE CONTRACTION OR SPASTICITY)
University of California, Berkeley, Publications in Pharmacology. Vol. 2, Pg. 231, 1949.
mouse LC inhalation > 90mg/m3/4H (90mg/m3)   Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 30(8), Pg. 35, 1965.
mouse LD50 oral 80mg/kg (80mg/kg) BEHAVIORAL: CHANGES IN MOTOR ACTIVITY (SPECIFIC ASSAY)

BEHAVIORAL: MUSCLE CONTRACTION OR SPASTICITY)

LUNGS, THORAX, OR RESPIRATION: DYSPNEA
Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 30(8), Pg. 35, 1965.
mouse LD50 subcutaneous 155mg/kg (155mg/kg)   Voprosy Onkologii. Problems of Oncology. For English translation, see PONCAU. Vol. 4, Pg. 659, 1958.
Link to PubMed
mouse LD50 unreported 220mg/kg (220mg/kg)   Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 37(2), Pg. 102, 1972.
rabbit LD50 unreported 375mg/kg (375mg/kg)   Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 37(2), Pg. 102, 1972.
rat LC inhalation > 90mg/m3/4H (90mg/m3)   Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 30(8), Pg. 35, 1965.
rat LD50 oral 330mg/kg (330mg/kg) LIVER: OTHER CHANGES

BLOOD: NORMOCYTIC ANEMIA
Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 29(11), Pg. 51, 1985.
rat LD50 unreported 565mg/kg (565mg/kg)   Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 37(2), Pg. 102, 1972.
rat LDLo skin 2gm/kg (2000mg/kg)   "Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982Vol. -, Pg. 50, 1982.

Dicyclohexylammonium nitrite Consensus Reports

Reported in EPA TSCA Inventory.

Dicyclohexylammonium nitrite Safety Profile

Poison by ingestion and subcutaneous routes. Questionable carcinogen with experimental tumorigenic data. A flammable liquid. When heated to decomposition it emits very toxic fumes of HNO2 and NOx. See also NITRITES.
Safety Information of Dicyclohexylammonium nitrite (CAS NO.3129-91-7):
Hazard Codes: Xn
Risk Statements: 20/22 
20:  Harmful by inhalation 
22:  Harmful if swallowed 

Dicyclohexylammonium nitrite Standards and Recommendations

DOT Classification:  4.1; Label: Flammable Solid

Dicyclohexylammonium nitrite Specification

 Dicyclohexylammonium nitrite,its CAS NO. is 3129-91-7,the synonyms is Nitrous acid dicyclohexylamine ; n,n-Dicyclohexylammonium nitrite ; Dicyclohexylamine nitrite ; Dicyclohexylammonium nitrite ; Dodecahydrodiphenylamine nitrite ; Biscyclohexylaminenitrite ; Cyclohexanamine, n-cyclohexyl-, nitrite ; Cyclohexanamine,n-cyclohexyl-,nitrite .

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