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Dipropyl adipate

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Name

Dipropyl adipate

EINECS 203-371-9
CAS No. 106-19-4 Density 0.979
PSA 52.60000 LogP 2.45320
Solubility N/A Melting Point -15.7oC
Formula C12H22 O4 Boiling Point 144 ºC (10 mmHg)
Molecular Weight 230.304 Flash Point 140 ºC
Transport Information N/A Appearance Liquid.
Safety Moderately toxic by some routes. Experimental reproductive effects. An experimental teratogen. When heated to decomposition it emits acrid smoke and fumes. Risk Codes N/A
Molecular Structure Molecular Structure of 106-19-4 (Hexanedioic acid,1,6-dipropyl ester) Hazard Symbols N/A
Synonyms

Adipicacid, dipropyl ester (6CI,7CI,8CI); Hexanedioic acid, dipropyl ester (9CI);Adipic acid di-n-propyl ester; Di-n-propyl adipate; Dipropyl adipate; Dipropylhexanedioate; NSC 4894

Article Data 18

Dipropyl adipate Synthetic route

71-23-8

propan-1-ol

124-04-9

Adipic acid

106-19-4

di-n-propyl adipate

Conditions
ConditionsYield
With Fe(SO4)3 * xH2O In toluene for 2h; Heating;98%
With iron(III) perchlorate for 3h; Ambient temperature;95%
With [AlMo6]Anderson-type heteropoly acid at 100℃; for 8h;55%
124-04-9

Adipic acid

110-74-7

propyl methanoate

A

6939-72-6

Hexanedioic acid monopropyl ester

B

106-19-4

di-n-propyl adipate

Conditions
ConditionsYield
With Dowex 50W-X2 (50-100 mesh) In octane at 70℃; for 2.66667h;A 85%
B 6%
With Dowex 50Wx2 In octane at 70℃; for 2.66667h; Esterification;A 85%
B 6%
71-23-8

propan-1-ol

201230-82-2

carbon monoxide

106-99-0

buta-1,3-diene

106-19-4

di-n-propyl adipate

Conditions
ConditionsYield
With palladium(II) trifluoroacetate; toluene-4-sulfonic acid; 1,2-bis[di(t-butyl)phosphinomethyl]benzene In toluene at 120℃; under 30003 Torr; for 24h; Autoclave; Green chemistry; regioselective reaction;78%
With palladium(II) trifluoroacetate; HeMaRaphos; toluene-4-sulfonic acid In toluene at 120℃; under 30003 Torr; for 24h; regioselective reaction;88 %Chromat.
71-23-8

propan-1-ol

108-94-1

cyclohexanone

106-19-4

di-n-propyl adipate

Conditions
ConditionsYield
With boron trifluoride diethyl etherate; dihydrogen peroxide In diethyl ether at 92 - 94℃; for 1h;65%
71-23-8

propan-1-ol

124-04-9

Adipic acid

A

6939-72-6

Hexanedioic acid monopropyl ester

B

106-19-4

di-n-propyl adipate

Conditions
ConditionsYield
With sulfuric acid
With Candida antarctica lipase immobilized on polyacrylic resin In 1,4-dioxane at 60℃; for 3h; Title compound not separated from byproducts;
With Candida antarctica lipase immobilized on polyacrylic resin In 1,4-dioxane for 3h; microwave irradiation; Title compound not separated from byproducts;
925-60-0

n-propyl acrylate

106-19-4

di-n-propyl adipate

Conditions
ConditionsYield
With hydrogenchloride; amalgamated potassium; water
106-19-4

di-n-propyl adipate

Conditions
ConditionsYield
In various solvent(s) at 270℃; Rate constant;
106-19-4

di-n-propyl adipate

A

187737-37-7

propene

B

74-98-6

propane

Conditions
ConditionsYield
With quinoline at 270℃; Rate constant;
106-19-4

di-n-propyl adipate

62-53-3

aniline

40832-99-3

N-phenylazepane

Conditions
ConditionsYield
With methanesulfonic acid; hydrogen; tris(acetylacetonato)ruthenium(III); [2-((diphenylphospino)methyl)-2-methyl-1,3-propanediyl]bis[diphenylphosphine] In 1,4-dioxane at 220℃; under 7500.75 Torr; for 42h;93 %Chromat.

Dipropyl adipate Chemical Properties

IUPAC Name: Dipropyl hexanedioate
The MF of Dipropyl adipate (CAS NO.106-19-4) is C12H22O4.

             
The MW of Dipropyl adipate (CAS NO.106-19-4) is 230.3.
Synonyms of Dipropyl adipate (CAS NO.106-19-4): Adipic acid, dipropyl ester ; Adipicacid,dipropylester ;  Dipropylhexanedioate ; Hexanedioicacid,dipropylester
Product Categories: Fatty Acid Esters (Plasticizer);Functional Materials;Plasticizer
Index of Refraction: 1.436 
EINECS: 203-371-9
Density: 0.985 g/ml 
Flash Point: 123.3 °C
Boiling Point: 274.3 °C

Dipropyl adipate Uses

  Dipropyl adipate (CAS NO.106-19-4) is used to make functional materials and plasticizer.

Dipropyl adipate Toxicity Data With Reference

1.    

ipr-rat LD50:3786 mg/kg

    JPMSAE    Journal of Pharmaceutical Sciences. 62 (1973),1596.

Dipropyl adipate Consensus Reports

Reported in EPA TSCA Inventory.

Dipropyl adipate Safety Profile

Moderately toxic by some routes. Experimental reproductive effects. An experimental teratogen. When heated to decomposition it emits acrid smoke and fumes.Safety information of Dipropyl adipate (CAS NO.106-19-4):
Safety Statements 
24/25 Avoid contact with skin and eyes
RTECS  AV1740000

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