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Cas Database |
| Name |
Ethyl diethoxyphosphinylformate |
EINECS | 216-016-8 |
| CAS No. | 1474-78-8 | Density | 1.11 |
| PSA | 71.64000 | LogP | 2.40900 |
| Solubility | N/A | Melting Point |
N/A |
| Formula | C7H15 O5 P | Boiling Point | 135 ºC (12 mmHg) |
| Molecular Weight | 210.167 | Flash Point | >110 ºC |
| Transport Information | N/A | Appearance | Clear, colorless liquid. |
| Safety | S24/25 | Risk Codes | 36/37/38-43 |
| Molecular Structure |
|
Hazard Symbols | Xi |
| Synonyms |
Formicacid, phosphono-, triethyl ester (7CI,8CI); Phosphinecarboxylic acid,diethoxy-, ethyl ester, oxide (9CI); Diethyl (ethoxycarbonyl)phosphonate;Diethyl carbethoxyphosphonate; Ethyl diethylphosphonoformate; NSC 108684;Triethyl carboxyphosphonate; Triethyl phosphonoformate |
Article Data | 13 |
Ethyl diethoxyphosphinylformate Synthetic route
| Conditions | Yield |
|---|---|
| 91% |
- 30410-95-8
dimethoxymethyl phosphonic acid dimethyl ester
- 1474-78-8
triethyl phosphonoformate
| Conditions | Yield |
|---|---|
| With N-Bromosuccinimide In benzene for 1h; Heating; argon atmosphere; | 80% |
- 17997-33-0
diethyl(diethoxymethyl)phosphonate
- 1474-78-8
triethyl phosphonoformate
| Conditions | Yield |
|---|---|
| With N-Bromosuccinimide In benzene for 1h; Heating; | 80% |
| With di-tert-butyl peroxide In chlorobenzene at 120℃; Rate constant; Mechanism; Product distribution; various solvents, various temperature; |
- 2303-76-6, 118080-94-7
sodium diethyl phosphite
- 541-41-3
chloroformic acid ethyl ester
- 1474-78-8
triethyl phosphonoformate
| Conditions | Yield |
|---|---|
| With diethyl ether | |
| With Petroleum ether |
- 64-17-5
ethanol
- 20537-54-6
N,N'-Bis-(O,O-diaethyl-phosphonocarbonyl)-sulfonyldiamid
- 1474-78-8
triethyl phosphonoformate
| Conditions | Yield |
|---|---|
| for 13h; Heating; |
- 16540-25-3
oxophosphonoacetic acid triethyl ester
- 1474-78-8
triethyl phosphonoformate
| Conditions | Yield |
|---|---|
| at 150℃; |
- 34909-25-6
diethyl <(ethylenedioxy)methyl>phosphonate
- 1474-78-8
triethyl phosphonoformate
| Conditions | Yield |
|---|---|
| With di-tert-butyl peroxide In chlorobenzene at 120℃; Rate constant; Mechanism; Product distribution; various solvents, various temperature; |
- 1474-78-8
triethyl phosphonoformate
- 99-61-6
3-nitro-benzaldehyde
- 621-19-2
(E)-ethyl 3-(3-nitrophenyl)acrylate
| Conditions | Yield |
|---|---|
| With lithium hydroxide In tetrahydrofuran at 20℃; Horner-Wadsworth-Emmons Olefination; | 97% |
Ethyl diethoxyphosphinylformate Chemical Properties
Molecular Structure:
Molecular Formula: C7H15O5P
Molecular Weight: 210.1648
IUPAC Name: Ethyl diethoxyphosphorylformate
Synonyms of Ethyl diethoxyphosphinylformate (CAS NO.1474-78-8): AI3-18561 ; Diethyl carbethoxyphosphonate ; Diethyl ethoxycarbonylphosphonate ; EINECS 216-016-8 ; Formic acid, phosphono-, triethyl ester ; NSC 108684 ; Phosphinecarboxylic acid, diethoxy-, ethyl ester, oxide ; Triethyl carboxyphosphonate ; Triethyl phosphonoformate ; Triethyl phosphonomethanoate ; Diethyoxyphosphinecarboxylic acid, ethyl ester, oxide ; Phosphinecarboxylic acid, 1,1-diethoxy-, ethyl ester, 1-oxide
CAS NO: 1474-78-8
Product Categories: Organic Building Blocks ; Phosphonates/Phosphinates ; Phosphorus Compounds
Index of Refraction: 1.419
Molar Refractivity: 46.61 cm3
Molar Volume: 184.4 cm3
Surface Tension: 34.4 dyne/cm
Density: 1.139 g/cm3
Flash Point: 128 °C
Enthalpy of Vaporization: 50.28 kJ/mol
Boiling Point: 264.9 °C at 760 mmHg
Vapour Pressure of Ethyl diethoxyphosphinylformate (CAS NO.1474-78-8): 0.00947 mmHg at 25°C
Ethyl diethoxyphosphinylformate Safety Profile
Hazard Codes of Ethyl diethoxyphosphinylformate (CAS NO.1474-78-8): 
Xi
Risk Statements: 36/37/38
R36/37/38: Irritating to eyes, respiratory system and skin.
Safety Statements: 24/25-36/37-26
S24/25: Avoid contact with skin and eyes.
S36/37: Wear suitable protective clothing and gloves.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
WGK Germany: 3
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