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Ethylaluminum sesquichloride

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Name

Ethylaluminum sesquichloride

EINECS 235-137-7
CAS No. 12075-68-2 Density 0.904 g/mL at 25 °C
PSA 0.00000 LogP 4.99020
Solubility N/A Melting Point -50 °C(lit.)
Formula C6H15Al2Cl3 Boiling Point 204 °C(lit.)
Molecular Weight 247.507 Flash Point -1 °F
Transport Information UN 3394 4.2/PG 1 Appearance clear colorless solution
Safety 16-26-36/37/39-45-27 Risk Codes 15-17-23/24/25-34-14/15-14
Molecular Structure Molecular Structure of 12075-68-2 (ETHYLALUMINUM SESQUICHLORIDE) Hazard Symbols FlammableF, CorrosiveC
Synonyms

Aluminum,trichlorotriethyldi- (6CI,7CI,8CI);Sesquiethylaluminum chloride;Trichlorotriethyldialuminium;Trichlorotriethyldialuminum;Triethylaluminum sesquichloride;Triethyldialuminum trichloride;

Article Data 5

Ethylaluminum sesquichloride Chemical Properties

IUPAC Name: Chloro-dichloronio-ethylalumanuide ; Diethylalumanide (12075-68-2 )
Product Categories: Organometallics ; Chemical Synthesis ; Organoaluminum ; Organometallic Reagents 
Molecular Structure:  
Molecular Formula : C6H15Al2Cl3
Molecular Weight:  247.50
CAS Registry Number:  12075-68-2
EINECS : 235-137-7
Density:  0.904
Flash point  -18 ºC
Mol File: 12075-68-2.mol
Flash Point: -1°C 
Boiling Point:  204 °C(lit.) 
Melting point: -50 °C(lit.)
storage temp:  water-free area
Appearance:Triethyldialuminum trichloride  (12075-68-2 ) is clear colorless solution

Ethylaluminum sesquichloride Consensus Reports

Reported in EPA TSCA Inventory.

Ethylaluminum sesquichloride Safety Profile

Hazard Codes  F,C
Risk Statements  17-23/24/25-34-14/15
17:  Spontaneously flammable in air
34:  Triethyldialuminum trichloride  (12075-68-2 ) can causes burns
14/15:  Reacts violently with water, liberating extremely flammable gases 
23/24/25:  Toxic by inhalation, in contact with skin and if swallowed      
Safety Statements  16-26-36/37/39-45-27
16:  Keep away from sources of ignition - No smoking 
26:  In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 
27:  Take off immediately all contaminated clothing 
45:  In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) 
36/37/39:  Wear suitable protective clothing, gloves and eye/face protection  
RIDADR  UN 3394 4.2/PG 1
RTECS  BD1950000
HazardClass  4.2
PackingGroup  I

Ethylaluminum sesquichloride Standards and Recommendations

ACGIH TLV: TWA 2 mg(Al)/m3

Ethylaluminum sesquichloride Specification

1.General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Will burn if involved in a fire. Water Reactive. Material will react with water and may release a flammable and/or toxic gas. Flammable liquid and vapor.
2.Extinguishing Media: Do NOT use halogenated agents. Use dry sand, dry chemical, soda ash or lime. DO NOT USE WATER OR FOAM. 
Handling: Do not allow water to get into the container because of violent reaction. Use spark-proof tools and explosion proof equipment. Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Take precautionary measures against static discharges. Use and store under nitrogen. 3.Do not allow contact with water. Use only in a chemical fume hood.
4.Storage: Keep Triethyldialuminum trichloride  (12075-68-2 ) away from sources of ignition. Store in a cool, dry place. Store in a tightly closed container. Flammables-area. Corrosives area. Water free area. Store protected from moisture. Store under nitrogen. 

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