η2-Co-ordination in a 1,3-Diphospha-allene complex of Platinum(O). Synthesis and Solution (31)P N.M.R. Spectrum of (R = 2,4,6-(Bu-t)3C6H2)

DOI: 10.1039/c39850000946

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Journal of the Chemical Society. Chemical communications p. 946 - 947 (1985)

Update date:2022-08-04

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Authors:

Akpan, Clara Afiong

Meidine, Mohamed F.

Nixon, John F.

Yoshifuji, Masaaki

Toyota, Kozo

Inamoto, Naoki

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Article abstract of DOI:10.1039/c39850000946

The first example of a co-ordination complex containing the novel diphospha-allene ligand RP=C=PR (R = 2,4,6-(Bu-t)3C6H2) is reported and solution (31)P n.m.r. studies indicate that in solution the ligand is bonded in an η²-fashion to the metal as in the isoelectronic allene and CS2 (or CO2) complexes.

Full text of DOI:10.1039/c39850000946

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