Journal of the Chemical Society. Chemical communications p. 946 - 947 (1985)
Update date:2022-08-04
Topics:
Akpan, Clara Afiong
Meidine, Mohamed F.
Nixon, John F.
Yoshifuji, Masaaki
Toyota, Kozo
Inamoto, Naoki
The first example of a co-ordination complex containing the novel diphospha-allene ligand RP=C=PR (R = 2,4,6-(Bu-t)3C6H2) is reported and solution (31)P n.m.r. studies indicate that in solution the ligand is bonded in an η2-fashion to the metal as in the isoelectronic allene and CS2 (or CO2) complexes.
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