Synthesis of (3S,4R)-Eldanolide and (5S,12R)-Leukotriene-B4 through Photolysis of Optically Active Hydroxy-7,7-dimethylbicycloheptanones

DOI: 10.1039/c39850001166

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1166 - 1168 (1985)

Update date:2022-07-30

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Authors:

Davies, H. Geoff

Roberts, Stanley M.

Wakefield, Basil J.

Winders, John A.

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Article abstract of DOI:10.1039/c39850001166

Photoisomerisation of 3-hydroxy-7,7-dimethylbicyclo<3.2.0>heptan-6-ones is the key step in a new route to the pheromone eldanolide while leukotriene-B4 is available through a photolytic retro<2+2> reaction of 2-hydroxy-7,7-dimethylbicyclo<3.2.0>heptan-6-ones.

Full text of DOI:10.1039/c39850001166

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