Tetrahedron Letters p. 4253 - 4256 (1985)
Update date:2022-08-03
Topics:
Grundon, Michael F.
Ramachandran, V. N.
Reversible Claisen rearrangement of 3-(3,3-dimethylallyl)-4-(3,3-dimethylallyloxy)quinolin-2-one (5) furnished the alkaloid, buchapsine (6), which readily lost the 1,1-dimethylallyl group; a mechanism for the cleavage reaction is proposed.
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(1958)
