α-Secondary Dialkylallylamines from Aminonitriles via the Bruylants Reaction

DOI: 10.1055/s-1985-31330

Source and publish data:

Synthesis p. 743 - 748 (1985)

Update date:2022-08-04

Topics:

Authors:

Ahlbrecht, Hubertus

Dollinger, Horst

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Article abstract of DOI:10.1055/s-1985-31330

The pracitally unknown α-secondary allylamines 1 have been synthesised in good to very good yields by reaction of allylaminonitriles 7 with Grignard reagents.The reaction is regio- and stereoselective and can also be run with α-aminonitriles 9 and vinyl Grigrand reagents.

Full text of DOI:10.1055/s-1985-31330

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