Facial discrimination in monoarylporphyrins: Synthesis and stereochemical behaviour of bis(ligated) monospirobifluorenylporphyrin ruthenium complexes

DOI: 10.1016/j.inoche.2007.02.006

Source and publish data:

Inorganic Chemistry Communications p. 627 - 630 (2007)

Update date:2022-08-02

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Authors:

Poriel, Cyril

Martail, Audrey

Simonneaux, Gérard

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Article abstract of DOI:10.1016/j.inoche.2007.02.006

Condensation of dipyrromethane, pyrrole-2-carbaldehyde with either 9,9′-spirobifluorene or fluorene aldehyde yields new meso-monosubstituted, β-unsubstituted porphyrins. The large size of spirobifluorene hinders the rotation around the C_meso-C<

Full text of DOI:10.1016/j.inoche.2007.02.006

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