Novel Benzeneosmium Complexes containing Alkynyl, Vinyl, and Vinylidene Groups as Ligands

DOI: 10.1039/c39850001145

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1145 - 1146 (1985)

Update date:2022-09-26

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Authors:

Weinand, Rudolf

Werner, Helmut

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Article abstract of DOI:10.1039/c39850001145

The complex C6H6(=C=CHPh)(PPrⁱ3) has been prepared from 2 via alkynyl(iodo)-, vinyl(hydrido)-, and vinyl(halogeno)-osmium compounds as precursors; it reacts with sulphur, selenium, and CuCl by electrophilic addition to the Os=C bond.

Full text of DOI:10.1039/c39850001145

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