Journal of the American Chemical Society p. 2641 - 2645 (1986)
Update date:2022-08-04
Topics:
Kitamura, Tsugio
Kobayashi, Shinjiro
Taniguchi, Hiroshi
Photolysis of vinyl halides in the presence of copper(II) salts in a significant suppression of product formation derived from vinyl radicals.Photolysis of 1,1-diaryl-2-bromopropenes in the presence of copper(II) salts yielded no 1,1-diaryl-2-propenes.Photolysis of other vinyl halides, i.e., 1,1-diaryl-2-iodopropenes, 1,1-diaryl-2-bromoethylenes, and 1-bromo-2-(p-methoxyphenyl)ethylene, also led to a large decrease in the yields of the reduced olefins derived from the vinyl radicals.Copper(II) triflate was found to be more effective for the oxidation of vinyl radicals than copper(II) acetate.These reactions are explained by the intervention of vinylcopper intermediates and the formation of vinyl cations.
View MoreBeyond Pharmaceutical Co., Ltd
Contact:+86-571-8195-3185
Address:No. 13-1, Liansheng Road, Yuhang District
Shanxi Tongji Pharmaceuticals Co., Ltd.
Contact:+86-359-3024784
Address:Xikuang South Road, Ruicheng County , Shanxi
Dalian Synco Chemical Co., Ltd.
Contact:+86-411-83635150
Address:Rm 1004, 24, Tangshan Street, Dalian
Changzhou Welton Chemical Co., Ltd,
Contact:0086-519-85910828,85920537,85912897
Address:No.8 Jinlong Road, Binjiang Park, Changzhou, Jiangsu, China.
Taizhou Shengxing Chempharm Co.,Ltd
Contact:+86-576-88516600
Address:Yantou Chemical Zone Jiaojiang Taizhou Zhejiang China
Doi:10.1021/acs.joc.1c01290
(2021)Doi:10.1016/j.abb.2010.05.025
(2010)Doi:10.1007/BF00579146
(1985)Doi:10.1021/jo00362a007
(1986)Doi:10.1055/s-0036-1588126
(2017)Doi:10.1016/S0040-4020(98)00020-9
(1998)
