
Tetrahedron Letters p. 3977 - 3980 (1985)
Update date:2022-08-05
Topics:
Elkik, Elias
Imbeaux-Oudotte, Michele
Reaction of dimethyl-sulfoxonium methylide with non-halogenated α-ethylenic-ketones is known to lead to cyclopropyl derivatives.With α-fluoro α-ethylenic-ketones this reaction furnishes fluoro-epoxides, by addition of a methylene on carbonyl.
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(1996)