CETONES α-FLUORO α-ETHYLENIQUES: PREPARATION ET REACTION AVEC LE METHYLURE DE DIMETHYLSULFOXONIUM.

DOI: 10.1016/S0040-4039(00)98702-1

Source and publish data:

Tetrahedron Letters p. 3977 - 3980 (1985)

Update date:2022-08-05

Topics:

Authors:

Elkik, Elias

Imbeaux-Oudotte, Michele

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)98702-1

Reaction of dimethyl-sulfoxonium methylide with non-halogenated α-ethylenic-ketones is known to lead to cyclopropyl derivatives.With α-fluoro α-ethylenic-ketones this reaction furnishes fluoro-epoxides, by addition of a methylene on carbonyl.

Full text of DOI:10.1016/S0040-4039(00)98702-1

Products guided by the article

Product name:2-((Z)-1-Fluoro-3,3-dimethyl-but-1-enyl)-2-phenyl-oxirane

Cas No:101560-21-8

R&D Labs maybe for 101560-21-8

N&R INDUSTRIES,INC

Contact:Tel:+86-29-88764861 Fax:+86-29-88764861

Address:Rm#2107, Block A, Epin Meidao Building, Gaoxin Rd, Hi-Tech Zone, Xi’an, China
Jiaxing Barton Chemicals

website:http://www.chinabarton.com

Contact:+86-573-82719618

Address:No. 162 Fumin Road, Honghe Town,
Antaeus Bio-technology Co., LTD(expird)

Contact:021-31252569

Address:shanghai pudong
Changzhou Sunlight Pharmaceutical Co., Ltd.

Contact:+86-519-83131668;83139028;83138042;83137041

Address:JiuliStreet, Benniu Town Changzhou City, Jiangsu Province
Anhui Sunsing Chemicals Co.,Ltd

website:http://www.sunsingchem.com

Contact:0086-566-2023179

Address:Jin An industry park, Chizhou economic technical development zone, Anhui

Relevant to this article

Palladium-Catalyzed Asymmetric Allylic Fluoroalkylation/Trifluoromethylation

Doi:10.1021/jacs.9b06231
(2019)
Chemoselective reductive alkynylation of tertiary amides by Ir and Cu(i) bis-metal sequential catalysis

Doi:10.1039/c6cc05318a
(2016)
Diastereocontrol in open-chain nucleophilic attack on a double bond adjacent to a stereogenic centre carrying a silyl group

Doi:10.1039/b305882d
(2003)
Modulators of hERAP2 discovered by high-throughput screening

Doi:10.1016/j.ejmech.2020.113053
(2021)
The fragmentation of alkoxychlorocarbenes in hydrocarbon solvents and in low temperature argon matrixes

Doi:10.1021/jp0217076
(2002)
Large scale synthesis of the high quality indoloquinone antitumor agent EO 9 via [bis(trifluoroacetoxy)iodo]benzene oxidation of 4-aminoindole

Doi:10.1055/s-1996-4270
(1996)

Article Doi