Journal of the American Chemical Society p. 4586 - 4594 (1986)
Update date:2022-08-04
Topics: NMR spectroscopy Catalyst Total synthesis Reagent Stereoselective Purification Substrate Chiral Auxiliary Chemical Reaction
Hecker, Scott J.
Heathcock, Clayton H.
A total syntheses of (+)-dihydromevinolin (2b) is presented, as well as the preparation of three analogues (62, 63, and 64) for assessment of their biological activity.Base-promoted fragmentation of the tosylhydrazone (20) of key intermediate 6 affords ac
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