Aggregative activation in heterocyclic chemistry. Part 4. Metallation of 2-methoxypyridine: Unusual behaviour of the new unimetal superbase BuLi-Me2N(CH2)2OLi (BuLi-LiDMAE)

DOI: 10.1039/a701914i

Source and publish data:

Journal of the Chemical Society. Perkin transactions I p. 3071 - 3080 (1997)

Update date:2022-08-02

Topics:

Authors:

Gros, Philippe

Fort, Yves

Caubere, Paul

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/a701914i

A series of potential unimetal superbases BuLi-ROLi has been studied in order to increase the basicity/ nucleophilicity ratio ([B/N]R) of BuLi. The best [B/N]R ratio is found with BuLi-LiDMAE. This complex base apparently metallates 2-methoxypyridine at t

Full text of DOI:10.1039/a701914i

Products guided by the article

Product name:2-butyl-2,5-dihydro-6-methoxypyridine

Cas No:101773-64-2

R&D Labs maybe for 101773-64-2

Shanghai Longschem Co.,Ltd

Contact:021-36356756

Address:Room601,Building No.14,280 Yangcheng Road,Shanghai
WUXI HONOR SHINE CHEMICAL CO.,LTD

Contact:+86-510-83593312

Address:No.1699 Huishan avenue,Huishan district,Wuxi ,Jiangsu,China,214177.(Wuxi Huishan Ecomonic Develop Zone )
Luoyang Aoda chemical Co.,Ltd.

Contact:+86-379-67518785 67516588

Address:MiaoWan industry district,YanShi City,Henan,China
BrightGene Bio-Medical Technology Co., Ltd.

website:https://en.bright-gene.com/

Contact:+86-512-62551801

Address:Building C25 - C31, No. 218 Xinghu Road, Suzhou Industrial Park, Suzhou, Jiangsu, China.
ANTAI BIO-TECH CO LTD

website:http://www.antaibio.com

Contact:0086-21-65663057

Address:Room 2108, Building 2，No. 489 Zhengli Road，200433

Relevant to this article

Synthesis and Cytotoxic Evaluation of Monocarbonyl Analogs of Curcumin as Potential Anti-Tumor Agents

Doi:10.1002/ddr.21291
(2016)
Rhodium(III)-Catalyzed ortho-Heteroarylation of Phenols through Internal Oxidative C-H Activation: Rapid Screening of Single-Molecular White-Light-Emitting Materials

Doi:10.1002/anie.201507272
(2015)
Total synthesis of (R)-tylophorine by using an asymmetric hydrogenation of the allyl alcohol

Doi:10.1016/j.tetlet.2018.04.052
(2018)
Cobalt(II) complexes of new biomimetic polydentate amide: Spectroscopic, kinetics of thermal decomposition and XRPD studies

Doi:10.1016/j.saa.2007.05.045
(2008)
Doi:10.1039/jr9600003521
(1960)
Catalyst activity or stability: The dilemma in Pd-catalyzed polyketone synthesis

Doi:10.1039/c3dt51425k
(2013)

Article Doi