Epoxy-annulations by reactions of α-amido ketones with vinyl sulfonium salts. Reagent versus substrate control and kinetic resolution

DOI: 10.1021/ol800318h

Source and publish data:

Organic Letters p. 1501 - 1504 (2008)

Update date:2022-08-05

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Authors:

Unthank, Matthew G.

Tavassoli, Bahareh

Aggarwal, Varinder K.

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Article abstract of DOI:10.1021/ol800318h

(Chemical Equation Presented) Diphenyl vinyl sulfonium salt and chiral amido-ketones undergo highly diastereoselective epoxy-annulation reactions in good yield. The use of a chiral vinyl sulfonium salt dominates the stereochemical outcome of the annulatio

Full text of DOI:10.1021/ol800318h

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