Tetrahedron Letters p. 1077 - 1080 (1996)
Update date:2022-08-03
Topics:
Abiko, Atsushi
Masamune, Satoru
The asymmetric Horner-Emmons reaction of the phosphonate derived from a chiral benzopyrano-isoxazolidine (with 4-substituted cyclohexanones) proceeded in high diastereoselectivity with the aid of KHMDS and 18-crown-6 ether. Enantiomerically pure, axially dissymmetric cyclohexylidene alcohols, aldehydes and ketones were obtained from the diastereomerically pure Horner-Emmons products in a single step.
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