Tetrahedron Letters p. 1077 - 1080 (1996)
Update date:2022-08-03
Topics:
Abiko, Atsushi
Masamune, Satoru
The asymmetric Horner-Emmons reaction of the phosphonate derived from a chiral benzopyrano-isoxazolidine (with 4-substituted cyclohexanones) proceeded in high diastereoselectivity with the aid of KHMDS and 18-crown-6 ether. Enantiomerically pure, axially dissymmetric cyclohexylidene alcohols, aldehydes and ketones were obtained from the diastereomerically pure Horner-Emmons products in a single step.
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Doi:10.1016/0040-4020(96)00337-7
(1996)Doi:10.1055/s-0031-1289998
(2012)Doi:10.1248/cpb.45.1156
(1997)Doi:10.1021/jo00237a019
(1988)Doi:10.1016/S0277-5387(00)84076-0
(1985)Doi:10.1016/S0968-0896(00)00142-5
(2000)
