Synthetic study on gymnodimine: Highly stereoselective construction of substituted tetrahydrofuran and cyclohexene moieties

DOI: 10.1055/s-1997-1075

Source and publish data:

Synlett p. 1417 - 1419 (1997)

Update date:2022-09-26

Topics:

Authors:

Ishihara, Jun

Miyakawa, Jun

Tsujimoto, Takashi

Murai, Akio

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Article abstract of DOI:10.1055/s-1997-1075

The synthetic studies on gymnodimine, a shellfish toxin, are described. This marine toxin consists of 16-membered carbocycle, tetrahydrofuran, and spiro-imine moieties. Our synthetic strategy involves the stereoselective allylation of tetrahydrofuran compound and the exo-selective intramolecular Diels-Alder reaction.

Full text of DOI:10.1055/s-1997-1075

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