On-site modification of oligopeptides: Conversion of seryl into (exo)-2-azabicyclo[2.2.1]hept-5-ene-3-carbonyl residues

DOI: 10.1016/0040-4039(94)02432-B

Source and publish data:

Tetrahedron Letters p. 861 - 864 (1995)

Update date:2022-08-02

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Authors:

Jaeger, Martin

Polborn, Kurt

Steglich, Wolfgang

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Article abstract of DOI:10.1016/0040-4039(94)02432-B

Diels-Alder addition of cyclopentadiene to Z-valyl-dehydroglycine methyl ester and similar peptides affords conformationally constrained (exo)-2-azabicyclo[2.2.1]hept-5-ene-3-carbonyl derivates 4 with high stereoselectivity. The stereochemistry of the cyc

Full text of DOI:10.1016/0040-4039(94)02432-B

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