Journal of Organic Chemistry p. 7364 - 7367 (1993)
Update date:2022-08-04
Topics:
De Vargas
Setti
Aimar
De Rossi
The reactions of 3-butenyl 2,4-dinitrophenyl ether (1), allyl 2,4- dinitrophenyl ether (5), and n-butyl 2,4-dinitrophenyl ether (6) with KOH in two DMSO-water mixtures (50% v/v and 70% v/v) were studied. In all cases, no evidence was found for a single electron transfer mechanism; 2,4- dinitrophenol was the only product formed. The reaction follows the classical S(N)Ar mechanism. The order of reactivity is 5 > 1 > 6 in both solvents, although the reactivities differ only by factors of 1.4 and 2 in 50 and 70% DMSO, respectively.
View MoreWuhan Kemi-Works Chemical Co., Ltd
website:http://www.kemiworks.com
Contact:86-27-85736489
Address:Rm. 1503, No. 164, Jianghan North Rd., Wuhan, 430022 China
website:https://www.bocsci.com/
Contact:1-631-485-4226
Address:Ramsey Road
Contact:+86-533-3112891
Address:zibo
Nanjing Raise Pharmatech Co., Ltd
website:http://www.raisechem.com
Contact:+86-25-58649566
Address:B381,No.606,Ningliu Road,Jiangbei New Area,Nanjing,Jiangsu Province,China
Contact:+86-25-83719363
Address:106-7 Chunnan Rd, Chunxi Town, Gaochun, Nanjing, China
Doi:10.1134/S1070328412010034
(2012)Doi:10.1021/jm00159a019
(1986)Doi:10.1016/j.bmc.2008.01.042
(2008)Doi:10.1016/S0040-4039(00)99301-8
(1989)Doi:10.1021/jo01369a017
(1954)Doi:10.1016/j.ica.2019.02.007
(2019)
