Tetrahedron p. 9079 - 9086 (1996)
Update date:2022-09-26
Topics:
Agami, Claude
Bihan, Dominique
Puchot-Kadouri, Catherine
Iminium ions derived from a condensation of glyoxal and N-methyl (R)-phenylglycinol react with allylic silanes (trimethylallyl and trimethylmetallylsilanes) and enoxysilanes (2-trimethylsilyloxypropene and 2-trimethylsilyloxystyrene). These reactions proceed in a totally stereoselective way as evidenced by a chemical correlation and an X-Ray analysis of a compound related to both series of experiments.
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