Reactions of glyoxal-derived iminium ions with unsaturated silyl and silyloxy reagents

DOI: 10.1016/0040-4020(96)00450-4

Source and publish data:

Tetrahedron p. 9079 - 9086 (1996)

Update date:2022-09-26

Topics:

Authors:

Agami, Claude

Bihan, Dominique

Puchot-Kadouri, Catherine

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Article abstract of DOI:10.1016/0040-4020(96)00450-4

Iminium ions derived from a condensation of glyoxal and N-methyl (R)-phenylglycinol react with allylic silanes (trimethylallyl and trimethylmetallylsilanes) and enoxysilanes (2-trimethylsilyloxypropene and 2-trimethylsilyloxystyrene). These reactions proceed in a totally stereoselective way as evidenced by a chemical correlation and an X-Ray analysis of a compound related to both series of experiments.

Full text of DOI:10.1016/0040-4020(96)00450-4

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