REACTIONS OF AMINES AND RELATED SPECIES WITH TRANSITION METAL PEROXO COMPLEXES

DOI: 10.1016/0022-328X(85)80356-9

Source and publish data:

Journal of Organometallic Chemistry p. 291 - 300 (1985)

Update date:2022-08-04

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Authors:

Cenini, Sergio

Porta, Francesca

Pizzotti, Maddalena

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Article abstract of DOI:10.1016/0022-328X(85)80356-9

The reactions of amines and related species with molecular oxygen bound to a transition metal centre, are reviewed briefly.New results on the reactions of Pt(PPh3)2O2 with amine derivatives such as formanilides and imides are reported; from these reactions new amidohydroperoxoplatinum(II) complexes have been isolated.The related reaction of Pt(PPh3)2O2 with phenol is also described.A general mechanism for these deprotonation reactions is discussed.

Full text of DOI:10.1016/0022-328X(85)80356-9

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