Journal of Organometallic Chemistry p. 23 - 30 (1985)
Update date:2022-08-05
Topics:
Atwood, Jerry L.
Bott, Simon G.
Eaborn, Colin
El-Kheli, Mohammed N. A.
Smith, J. David
The compound (Me2PhSi)3CBF(OH), made by the hydrolysis of (Me2PhSi)3CBF2, appears to be the first fully characterised organofluorohydroxyborane.The coordination at boron is almost planar.Steric interactions from the large alkyl group, which adopts a propeller-like conformation, compress the F-B-O angle to 111(1) deg, prevent intermolecular hydrogen bonds, and largelu determine the crystal packing.As a result, the orientation of the FBO plane with respect to the three C-Si bonds is disordered: in one orientation (occupancy 40percent) the FBO plane eclipses one of the C-Si bonds and in the other (occupancy 60percent) the FBO plane is turned through approximately 90 deg.
Wuxi Forest Biological Co.,Ltd
Contact:+86-510-81602300
Address:Room 317,Building D, No.159 middle Chengjiang Road,Jiangyin Wuxi city.
Jiangxi Dongxu Chemical Science & Technology Co.,Ltd
Contact:+86-791-86899381
Address:Nanchang, Jiangxi, China
Hangzhou Mole's Science & Technology Co.,Ltd.(expird)
Contact:+86-571-56880228
Address:15F Guodu development Building, NO.182 Zhaohui Road
Zhejiang Kente Chemical Co.,Ltd.
Contact:86-0576-87651912
Address:No.7, Fengxi West Road, Modern Industrial Zone
Changzhou Anyi Biochem Co., Ltd.(expird)
Contact:+86-519-88836158
Address:no,51 caoda
Doi:10.1021/ic702279b
(2008)Doi:10.1021/jo00368a025
(1986)Doi:10.1002/ejoc.200700912
(2008)Doi:10.1016/j.bmcl.2006.11.004
(2007)Doi:10.1016/j.jfluchem.2009.12.017
(2010)Doi:10.1016/j.tetlet.2014.09.093
(2014)
