Journal of Organometallic Chemistry p. 23 - 30 (1985)
Update date:2022-08-05
Topics:
Atwood, Jerry L.
Bott, Simon G.
Eaborn, Colin
El-Kheli, Mohammed N. A.
Smith, J. David
The compound (Me2PhSi)3CBF(OH), made by the hydrolysis of (Me2PhSi)3CBF2, appears to be the first fully characterised organofluorohydroxyborane.The coordination at boron is almost planar.Steric interactions from the large alkyl group, which adopts a propeller-like conformation, compress the F-B-O angle to 111(1) deg, prevent intermolecular hydrogen bonds, and largelu determine the crystal packing.As a result, the orientation of the FBO plane with respect to the three C-Si bonds is disordered: in one orientation (occupancy 40percent) the FBO plane eclipses one of the C-Si bonds and in the other (occupancy 60percent) the FBO plane is turned through approximately 90 deg.
Chengda Pharmaceuticals Co., Ltd.
Contact:+86-573-84601188
Address:hengshan Road 5# in Jiashan, zhejiang
Beijing Wisdom Chemicals Co., Ltd.
Contact:+86-10-52350335
Address:F2, BLDG 19, Liando Valley U, Majuqiao, Tongzhou District, Beijing, China
Wuxi Highness Chemical Co.,Ltd
website:https://www.phtpharmatech.com/
Contact:86-510-81771080
Address:No58 East Xinguan Rd, Guanlin Town, Yixing City, Jiangsu China
Weihao Chemtech (ChangZhou) Co., Ltd.(expird)
Contact:051989185693
Address:NO 217 huangshan Rd ,Changzhou
Hebei Tianxiang Biological & Pharmaceutical Co., Ltd
Contact:86-0312-6615158
Address:No 42 fazhan street qingyuan county
Doi:10.1021/ic702279b
(2008)Doi:10.1021/jo00368a025
(1986)Doi:10.1002/ejoc.200700912
(2008)Doi:10.1016/j.bmcl.2006.11.004
(2007)Doi:10.1016/j.jfluchem.2009.12.017
(2010)Doi:10.1016/j.tetlet.2014.09.093
(2014)
