Journal of Organometallic Chemistry p. 23 - 30 (1985)
Update date:2022-08-05
Topics:
Atwood, Jerry L.
Bott, Simon G.
Eaborn, Colin
El-Kheli, Mohammed N. A.
Smith, J. David
The compound (Me2PhSi)3CBF(OH), made by the hydrolysis of (Me2PhSi)3CBF2, appears to be the first fully characterised organofluorohydroxyborane.The coordination at boron is almost planar.Steric interactions from the large alkyl group, which adopts a propeller-like conformation, compress the F-B-O angle to 111(1) deg, prevent intermolecular hydrogen bonds, and largelu determine the crystal packing.As a result, the orientation of the FBO plane with respect to the three C-Si bonds is disordered: in one orientation (occupancy 40percent) the FBO plane eclipses one of the C-Si bonds and in the other (occupancy 60percent) the FBO plane is turned through approximately 90 deg.
Hubei Xinghuo Chemical Co., Ltd.,
Contact:13925817279 13907299441
Address:Xinghuo Fine Chemistry Industrial Park, Xiaochang County, Hubei Province, China
ShiJiaZhuang Dowell Chemical Co.,Ltd.
website:http://www.dowechem.com
Contact:+86-13463963265
Address:Xiyangling village, high tech Zone, Shijiazhuang，Hebei, China
Shenzhen HwaGen Pharmaceutical Co., Ltd
website:http://www.rafflespt.com
Contact:+86-752-5538396
Address:Guangdong Huizhou China
Contact:+86-571-28186845
Address:Room 1224,Eastcom Mansion,398 Wensan Road,Hangzhou,310013 China
website:http://www.sdowchem.com
Contact:86-135-2193 7483
Address:8-106 taiyue building
Doi:10.1021/ic702279b
(2008)Doi:10.1021/jo00368a025
(1986)Doi:10.1002/ejoc.200700912
(2008)Doi:10.1016/j.bmcl.2006.11.004
(2007)Doi:10.1016/j.jfluchem.2009.12.017
(2010)Doi:10.1016/j.tetlet.2014.09.093
(2014)
