Journal of Organometallic Chemistry p. 23 - 30 (1985)
Update date:2022-08-05
Topics:
Atwood, Jerry L.
Bott, Simon G.
Eaborn, Colin
El-Kheli, Mohammed N. A.
Smith, J. David
The compound (Me2PhSi)3CBF(OH), made by the hydrolysis of (Me2PhSi)3CBF2, appears to be the first fully characterised organofluorohydroxyborane.The coordination at boron is almost planar.Steric interactions from the large alkyl group, which adopts a propeller-like conformation, compress the F-B-O angle to 111(1) deg, prevent intermolecular hydrogen bonds, and largelu determine the crystal packing.As a result, the orientation of the FBO plane with respect to the three C-Si bonds is disordered: in one orientation (occupancy 40percent) the FBO plane eclipses one of the C-Si bonds and in the other (occupancy 60percent) the FBO plane is turned through approximately 90 deg.
website:http://www.sigmaaldrich.com
Contact:800 558-9160
Address:Industriestrasse 25CH-9471 Buchs SGSwitzerland
Jiangsu Chiatai Qingjiang Pharmaceutical Co.,Ltd
Contact:+86-517-86283327
Address:9 North Hantai Road, Huaian, China
Xinchang Jiu Xin Pharmaceutical Co., Ltd
website:http://www.jiuxinpharm.com
Contact:86 137 5756 8585
Address:Poyang industry Park
NanJing Rate Biochemicals CO., LTD
Contact:+86-25-84931986
Address:NO. 1 Hongjing Road,Jiangning Science Park,Nanjing,China
Nanjing distinctions Medical Technology Co., Ltd.(expird)
Contact:+86-15996203785 13914714059
Address:nanjing,jiangsu , China
Doi:10.1021/ic702279b
(2008)Doi:10.1021/jo00368a025
(1986)Doi:10.1002/ejoc.200700912
(2008)Doi:10.1016/j.bmcl.2006.11.004
(2007)Doi:10.1016/j.jfluchem.2009.12.017
(2010)Doi:10.1016/j.tetlet.2014.09.093
(2014)
