Tetrahedron p. 4657 - 4666 (1985)
Update date:2022-08-04
Topics:
Lecea, B.
Aizpurua, J. M.
Palomo, C.
Synthetic utility of 1,1,3,3,-tetramethyldisiloxane (TMDS) reagent under the influence of iodine is described.TMDS reagent in combination with iodine produces alkyl iodides from carbonyl compounds and oxiranes in good to excellent yields.Reduction of quinones into hydroquinones is also described.The mentioned transformations are explained from mechanistic points of view.
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