A TANDEM MICHAEL REACTION-CYCLOALKYLATION UTILIZING 2-NITROPROPANE: A FACILE ROUTE TO THE ACID COMPONENT OF INSECTICIDAL PYRETHROIDS

DOI: 10.1016/S0040-4039(00)98342-4

Source and publish data:

Tetrahedron Letters p. 1923 - 1926 (1985)

Update date:2022-08-05

Topics: Facile Route Tandem Michael reaction 2-Nitropropane

Authors:

Babler, James H.

Spina, Kenneth P.

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Article abstract of DOI:10.1016/S0040-4039(00)98342-4

Treatment of three representative β-substituted-α-cyanoacrylates (2) with 2-nitropropane and potassium carbonate in refluxing ethanol afforded stereoselectively cyclopropanoid precursors (4) to 3-substituted-2,2-dimethylcyclopropanecarboxylic acids (7).

Full text of DOI:10.1016/S0040-4039(00)98342-4

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