Journal of the Chemical Society. Chemical communications p. 1754 - 1755 (1985)
Update date:2022-08-03
Topics:
Eaborn, Colin
Lickiss, Paul D.
Najim, Sabah T.
Romanelli, M. Novella
The compound R2C(SiMe2OMe)(SiMe2Cl) (R = SiMe3 throughout) reacts more rapidly with CF3CH2OH than with MeOH, and R2C(SiMe2OMe) reacts with EtOH to give exclusively the rearranged product R2C(SiMe2OEt)(SiPh2OMe), indicating that the rate-determining step of the solvolyses involves formation of a methoxy-bridged cation; migration of the OMe group also occurs in the reaction of the bromide with AgBF4.
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(1943)
