Journal of Organic Chemistry p. 10273 - 10287 (2013)
Update date:2022-08-03
Topics: Synthesis Catalyst Diastereoselective Allylic Acetates N-Protected
Cornil, Johan
Guerinot, Amandine
Reymond, Sebastien
Cossy, Janine
An ecofriendly and diastereoselective synthesis of cis-3,5-disubstituted isoxazolidines through the FeCl3·6H2O-catalyzed cyclization of δ-hydroxylamino allylic acetates is described. The synthetic potential of these products is highlighted by the preparation of several functionalized 1,3-amino alcohol precursors.
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