
Angewandte Chemie - International Edition p. 3568 - 3572 (2008)
Update date:2022-08-03
Topics:
Carpenter, Joseph
Northrup, Alan B.
Chung, DeMichael
Wiener, John J. M.
Kim, Sung-Gon
MacMillan, David W. C.
(Chemical Equation Presented) Look again: Highlights of the 20-step synthesis of callipeltoside C include the proline-catalyzed direct aldol reaction, enantioselective α-oxyamination reaction, and rapid access to the carbohydrate framework using a de novo synthesis protocol. Based on this work the previously assigned absolute configuration of the pendent 2-O-methylevalose unit has been revised.
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