Interconversion of Planar and Nonplanar N-Amido Ligands. Thermodynamically Stable Nonplanar N-Amido Ligands

DOI: 10.1021/ja00281a024

Source and publish data:

Journal of the American Chemical Society p. 6593 - 6605 (1986)

Update date:2022-08-05

Topics:

Authors:

Anson, Fred C.

Collins, Terrence J.

Gipson, Stephen L.

Keech, John T.

Krafft, Terry E.

Peake, Geoffrey T.

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Article abstract of DOI:10.1021/ja00281a024

An unexpected structural feature of organic amido ligating, polyanionic chelating (PAC) ligands has been discovered.Oxidation of trans-Os(η⁴-1)(t-Bupy)2, 3 (H₄1 = 1,2-bis(3,5-dichloro-2-hydroxybenzamido)-4,5-dichlorobenzene), by 1 fa

Full text of DOI:10.1021/ja00281a024

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Product name:[Os(C₆H₂Cl₂(NC(O)C₆H₂Cl₂O)2)(OP(C₆H₅)3)2]⁽¹⁺⁾*PF₆^(1-)= [Os(C₆H₂Cl₂(NCOC₆H₂Cl₂O)2)(OP(C₆H₅)3)2]PF₆

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