D-GLUCOPYRANOSYL PHENYLSULFONES: THEIR USE IN A STEREOCONTROLLED SYNTHESIS OF CIS 2,6-DISUBSTITUTED TETRAHYDROPYRANS (β-D-C-GLYCOSIDES)

DOI: 10.1016/S0040-4039(00)95049-4

Source and publish data:

Tetrahedron Letters p. 6189 - 6192 (1985)

Update date:2022-08-04

Topics:

Authors:

Beau, Jean-Marie

Sinay, Pierre

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Article abstract of DOI:10.1016/S0040-4039(00)95049-4

The lithiated anion derived from 3,4,6-tri-O-t-butyldimethylsilyl-2-deoxy-α,β-D-glucopyranosyl phenylsulfones 1 reacts with various electrophiles leading to alkylated products, precursors of β-D-C-glycosides 5a-g after stereocontrolled desulfonylation and

Full text of DOI:10.1016/S0040-4039(00)95049-4

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Product name:[(2R,4R,5R,6R)-4,5-Bis-(tert-butyl-dimethyl-silanyloxy)-6-(tert-butyl-dimethyl-silanyloxymethyl)-tetrahydro-pyran-2-yl]-((2R,3S,4S,5R,6S)-3,4,5-tris-benzyloxy-6-methoxy-tetrahydro-pyran-2-yl)-methanol

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