Auxiliary Structure and Asymmetric Induction in the Ene Reactions of Chiral Glyoxylates

DOI: 10.1021/jo00375a006

Source and publish data:

Journal of Organic Chemistry p. 4779 - 4784 (1986)

Update date:2022-08-04

Topics:

Authors:

Whitesell, James K.

Lawrence, Robert M.

Chen, Huang-Hsing

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Article abstract of DOI:10.1021/jo00375a006

A variety of chiral auxiliares (1a-13a) were prepared and tested for levels of asymmetric induction control in the ene reaction of chiral glyoxylates.Structural features required for high levels of control were defined by systematic modification of the auxiliary, providing systems with induction levels that ranged from 1.2 to 1 to better than 99.9 to 0.1.

Full text of DOI:10.1021/jo00375a006

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