A Concise Total Synthesis of (+/-)-Ipalbidine by Application of the Aldimine-Diene Cyclocondensation Reaction

DOI: 10.1021/jo00370a039

Source and publish data:

Journal of Organic Chemistry p. 3915 - 3916 (1986)

Update date:2022-09-26

Topics:

Authors:

Danishefsky, Samuel J.

Vogel, Claus

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00370a039

The scope of the diene-imine cyclocondensation reaction has been extended to the unstable Δ¹-pyrroline.Cyclocondensation of this compound with the silylketene acetal derived from ethyl 2-p-anisyl-3-methylcrotonate provides the basis for a rapid

Full text of DOI:10.1021/jo00370a039

Products guided by the article

Product name:Silane, (1,1-dimethylethyl)[[1-ethoxy-2-(4-methoxyphenyl)-3-methyl-1,3-butadien yl]oxy]dimethyl-, (Z)-

Cas No:104267-42-7

R&D Labs maybe for 104267-42-7

Shanghai Bosman Industrial Co., Ltd

Contact:86-21-63065878-8006

Address:Rm907, No.1611, North Sichuan Road, Hongkou District, Shanghai, 200080 China
PINGYUAN SIHUAN PHARMACEUTICAL CO., LTD

Contact:+86-531-55696072

Address:#2766,yinxiu Road, Economic Development Zone, Pingyuan Country, Shandong Province, China.
Jiaxing Anrui Material Technology Co., Ltd.

Contact:86-573-82651652 13305832579

Address:Room 407, Technology Building, 1369 Chennan Road, Jiaxing City, Zhejiang, China
Hangzhou Haiqiang Chemical Co.,Ltd.

Contact:+86-571-86960370

Address:Add: 5/F, Around Town North Road,No. 10, Hangzhou, Zhejiang,China
LIDE PHARMACEUTICALS LIMITED

website:http://www.lidepharma.com

Contact:+86-25-58409506

Address:N0.2-309 2/F Chungking Express Nos.36 Nathan Road，Kowloon, HK

Relevant to this article

Nucleophilic addition of phenol derivatives to methyl 1- nitrocyclopropanecarboxylates

Doi:10.1021/jo8010705
(2008)
Synthetic routes toward the trisaccharide related to the lipopolysaccharide of Burkholderia sp. HKI-402 (B4)

Doi:10.1039/c4ra03954h
(2014)
Doi:10.1021/ja01590a062
(1956)
Reductive silylation of Cp?UO₂(^MesPDI^Me) promoted by Lewis bases

Doi:10.1039/c5dt04776e
(2016)
General and practical conversion of aldehydes to homologated carboxylic acids

Doi:10.1021/ol8016484
(2008)
Palladium-catalyzed 1,2-addition of potassium aryl- and alkenyltrifluoroborates to aldehydes using thioether-imidazolinium carbene ligands

Doi:10.1021/jo801352h
(2008)

Article Doi