A Concise Total Synthesis of (+/-)-Ipalbidine by Application of the Aldimine-Diene Cyclocondensation Reaction

DOI: 10.1021/jo00370a039

Source and publish data:

Journal of Organic Chemistry p. 3915 - 3916 (1986)

Update date:2022-09-26

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Authors:

Danishefsky, Samuel J.

Vogel, Claus

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Article abstract of DOI:10.1021/jo00370a039

The scope of the diene-imine cyclocondensation reaction has been extended to the unstable Δ¹-pyrroline.Cyclocondensation of this compound with the silylketene acetal derived from ethyl 2-p-anisyl-3-methylcrotonate provides the basis for a rapid

Full text of DOI:10.1021/jo00370a039

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