Synthesis of Five- and Six-Membered Nitrogen Heterocycles via a Palladium(II)-Catalyzed Cyclization of Unsaturated Amides

DOI: 10.1021/jo00371a041

Source and publish data:

Journal of Organic Chemistry p. 4089 - 4090 (1986)

Update date:2022-08-05

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Authors:

Tamaru, Yoshinao

Hojo, Makoto

Kawamura, Shin-ichi

Yoshida, Zen-ichi

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Article abstract of DOI:10.1021/jo00371a041

Palladium(II)-catalyzed arylation of N-4-pentenyl-p-toluenesulfonamides 2 with ArSn(n-Bu)3 under oxidative conditions (CuCl2 in ether) provides either 2-arylpiperidines 5 or N-(chloro-5-arylpentyl)-p-toluenesulfonamides 6 depending on the kind of arylatin

Full text of DOI:10.1021/jo00371a041

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