Tetrahedron p. 5121 - 5132 (1985)
Update date:2022-09-26
Topics: Palladium Aryl Iodides Catalysed Reductive addition Propargyl alcohols
Arcadi, A.
Cacchi, S.
Marinelli, F.
The reaction of aryl iodides with ethynyl and arylethynyl, dialkyl carbinols in the presence of the tri- or dialkylammonium formate-palladium reagent provides a convenient route to γ,γ-diarylallylic alcohols.In the presence of arylethynyl, alkylcarbinols a lack of regioselectivity was observed and mixtures of β,γ-, γ,γ-diarylallylic alcohols, and α,β-unsaturated ketones were obtained.
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