Tetrahedron p. 5121 - 5132 (1985)
Update date:2022-09-26
Topics: Palladium Aryl Iodides Catalysed Reductive addition Propargyl alcohols γ,γ-diaryl allylic alcohols
Arcadi, A.
Cacchi, S.
Marinelli, F.
The reaction of aryl iodides with ethynyl and arylethynyl, dialkyl carbinols in the presence of the tri- or dialkylammonium formate-palladium reagent provides a convenient route to γ,γ-diarylallylic alcohols.In the presence of arylethynyl, alkylcarbinols a lack of regioselectivity was observed and mixtures of β,γ-, γ,γ-diarylallylic alcohols, and α,β-unsaturated ketones were obtained.
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Doi:10.1016/S0040-4039(00)85795-0
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