A CONVENIENT METHOD FOR GENERATION OF TIN(II) THIOESTER ENOLATE AND ITS REACTION WITH ALDEHYDE

DOI: 10.1246/cl.1986.213

Source and publish data:

Chemistry Letters p. 213 - 216 (1986)

Update date:2022-07-29

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Authors:

Mukaiyama, Teruaki

Yamasaki, Noritsugu

Stevens, Rodney W.

Murakami, Masahiro

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Article abstract of DOI:10.1246/cl.1986.213

Tin(II) enolates of thioesters are conveniently generated by the addition of stannous thiolates to ketenes.The tin(II) enolates thus formed react with aldehydes to afford the corresponding β-hydroxythioesters in a syn-selective manner.And this method is applied to an enantioselective formation of β-hydroxythioesters by the use of a chiral diamine as ligand.

Full text of DOI:10.1246/cl.1986.213

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