Chemistry Letters p. 213 - 216 (1986)
Update date:2022-07-29
Topics:
Mukaiyama, Teruaki
Yamasaki, Noritsugu
Stevens, Rodney W.
Murakami, Masahiro
Tin(II) enolates of thioesters are conveniently generated by the addition of stannous thiolates to ketenes.The tin(II) enolates thus formed react with aldehydes to afford the corresponding β-hydroxythioesters in a syn-selective manner.And this method is applied to an enantioselective formation of β-hydroxythioesters by the use of a chiral diamine as ligand.
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