Tetrahedron Letters p. 5253 - 5256 (1985)
Update date:2022-07-30
Topics:
Vice, Susan F.
Copeland, Catherine R.
Forsey, Steven P.
Dmitrienko, Gary I.
Selective side-chain modification of N-acyl-2,3-dialkylindoles at C-2, effected by bromination with NBS, and at C-3, effected via SN' type reactions of 2,3-dialkyl-2-methoxy-3-methylene indolines generated by low temperature bromination-methanolysis of N-acylindoles, can be usefully applied to the synthesis of substituted pyrrolo<1,2-a> indoles of potential value in the synthesis of mitosene analogs.
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