Tetrahedron Letters p. 5943 - 5946 (1985)
Update date:2022-09-26
Topics:
Barton, Derek H.R.
Crich, David
Potier, Pierre
The thermal and photochemical decomposition of a typical thiohydroxamic ester (mixed anhydride) doubly labelled with deuterium has shown the photochemical reaction to be a radical chain process, whereas about 20percent of the thermal reaction involves a cage mechanism.An improved route to 1-hydroxy-5-phenylthiazolin-2-thione is reported.
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