ON THE MECHANISM OF THE DECARBOXYLATIVE REARRANGEMENT OF THIOHYDROXAMIC ESTERS

DOI: 10.1016/S0040-4039(00)98267-4

Source and publish data:

Tetrahedron Letters p. 5943 - 5946 (1985)

Update date:2022-09-26

Topics:

Authors:

Barton, Derek H.R.

Crich, David

Potier, Pierre

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Article abstract of DOI:10.1016/S0040-4039(00)98267-4

The thermal and photochemical decomposition of a typical thiohydroxamic ester (mixed anhydride) doubly labelled with deuterium has shown the photochemical reaction to be a radical chain process, whereas about 20percent of the thermal reaction involves a cage mechanism.An improved route to 1-hydroxy-5-phenylthiazolin-2-thione is reported.

Full text of DOI:10.1016/S0040-4039(00)98267-4

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