Chemistry - A European Journal p. 5630 - 5637 (2008)
Update date:2022-08-04
Topics: Allylic Alcohols Boronic acid Ruthenium-catalyzed synthesis
Bouziane, Asmae
Helou, Marion
Carboni, Bertrand
Carreaux, Francois
Demerseman, Bernard
Bruneau, Christian
Renaud, Jean-Luc
Secondary allylic alcohols were synthesized from linear allylic halides or carbonates using a catalytic amount of a ruthenium complex in the presence of boronic acid. The effects of solvent, base, ruthenium precursor, and boronic acid were fully explored, and the scope of the reaction was extended to various sub-strates. We also describe a preliminary investigation towards an enantioselective process.
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(2008)
