Bulletin of the Chemical Society of Japan p. 83 - 88 (1986)
Update date:2022-07-30
Topics:
Sone, Tyo
Yokoyama, Ryoji
Okuyama, Yohko
Sato, Kazuaki
2-Chlorothiophene (1) was found to easily react with certain active aromatic compounds (2) in the presence of AlCl3 under mild conditions, yielding the corresponding 2-arylthiophenes (3) and 5-chloro-2,2'-bithienyl (5) as the main products.With compounds more reactive than 1, the formation of 3 predominated.Reactions of 1 with aryl alkyl ethers, for example, afforded the corresponding 3 in 44-83percent yields in one step.
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