HOMOCHIRAL KETALS IN ORGANIC SYNTHESIS. ENANTIOSELECTIVE SYNTHESIS OF PROPELLANONES

DOI: 10.1016/S0040-4039(00)84280-X

Source and publish data:

Tetrahedron Letters p. 1441 - 1444 (1986)

Update date:2022-07-29

Topics:

Authors:

Mash, Eugene A.

Nelson, Keith A.

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Article abstract of DOI:10.1016/S0040-4039(00)84280-X

Optically active propellanones have been prepared by diastereoselective cyclopropanation of homochiral ene ketals derived from 1,4di-O-benzyl-L-threitol and readily available bicyclic enones.

Full text of DOI:10.1016/S0040-4039(00)84280-X

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Product name:2,3,5,6,7,8-hexahydro-1H,4H-azulen-1-one cyclic (1S,2S)-1,2-bis-<(benzyloxy)methyl>ethylene acetal

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