Journal of Organic Chemistry p. 954 - 955 (1987)
Update date:2022-08-05
Topics:
Davis, Franklin A.
Sheppard, Aurelia C.
The first isolation and detection of α-siloxy epoxides 2 in the oxidation of silyl enol ethers 1 to α-hydroxy carbonyl compounds 4 (Rubottom reaction) by 2-sulfonyloxaziridine 5 is described.Asymmetric oxidation of silyl enol ethers by (+)-(R,R)-6 affords optically active α-hydroxy carbonyl compounds.
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