Journal of the Chemical Society. Chemical communications p. 1144 - 1146 (1984)
Update date:2022-09-26
Topics:
Meth-Cohn, Otto
Vuuren, Gerda van
Thiophene S,N-ylides readily react with electron-rich dienophiles yielding adducts formed by the efficient extrusion of acyl- and sulphonyl-thionitroso-compounds, themselves readily trapped by Diels-Alder or ene reactions; similar but slower cycloadditions occur with the analogous S,C-ylides, a potential source of thiocarbonyl derivatives.
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