ENANTIODIFFERENTIATING FUNCTIONALIZATION OF 2-SUBSTITUTED 1,3-PROPANEDIOLS VIA CHIRAL SPIROKETAL: TWO METHODS FOR THE PREPARATION OF (S)-2,3-DIMETHYLBUTYL PHENYL SULFIDES

DOI: 10.1016/S0040-4039(00)95573-4

Source and publish data:

Tetrahedron Letters p. 4181 - 4184 (1987)

Update date:2022-09-26

Topics: Functionalization Stereochemistry Chiral Resolution Preparation Method Enantiodifferentiating

Authors:

Harada, Toshiro

Wada, Isao

Oku, Akira

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Article abstract of DOI:10.1016/S0040-4039(00)95573-4

Enantioselective functionalization of 2-substituted 1,3-propanediols was realized by the utilization of triisobutylaluminium-promoted selective ring-cleavage reaction of spiroketals of l-menthone as a key reaction.

Full text of DOI:10.1016/S0040-4039(00)95573-4

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